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The (n-1)d shell of electron in d-block ...

The (n-1)d shell of electron in d-block elements is expanding and, therefore they have many physical and chemical properties in common. They show variable oxidation state and all are metals. The transition element i.e., d-block element show an unparallel tendency to form coordination compound with thhose groups which are able to donate an electron pair (i.e. lewis base).
Which of the following statement is incorrect?

A

Across a period from Sc to Cu the densities increase with increasing atomic number.

B

The melting point of transition elements rise to a maximum from Sc to Cr and then decreases from Fe to Zn.

C

Transition elements have high entahlpies of atomization and in 3d series regularly from Sc to Cu.

D

On going down a group from 3d to 6d series the stability of higher oxidation state increases with increasing atomic number.

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The correct Answer is:
C

(A), (B) and (D) All are correct statements.
There is drope in enthalpy of atomization at manganese because of half filled stable electronic configurtion leading to less mobilisation of electrons. This results in weaker metalic bonds.
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The (n-1)d shell of electron in d-block elements is expanding and, therefore they have many physical and chemical properties in common. They show variable oxidation state and all are metals. The transition element i.e., d-block element show an unparallel tendency to form coordination compound with thhose groups which are able to donate an electron pair (i.e. lewis base). Which one is most acidic?

Many ionic compounds in transition metal ions are colored because of the electronic transitions (in the visible range) involving d electrons, whereas the ionic compounds of the representative elements are usually colorless. Which of the following compounds is green in color?

Assing the reason for the following : (i) Transition metals generally form coloured compounds. (ii) Manganese exhibits highest oxidation state of +7 among the 3d series of transition elements.

(a) Define transition elements. (b) Give general electronic configuration of f-block elements.(c ) Most of transition elements are coloured, why? (d ) Transition elements show variable oxidation states, why?

The transition element ( with few exceptions ) show a large number of oxidation states . The various oxidation states are related to the electronic configuration of their atoms. The variable oxidation states of a transition metal is due to the involvement of (n-1)d and outer ns electrons . For the first five elements of 3d transition series , the minimum oxidation state is equal to the number of electrons in 4s shell and the maximum oxidation state is equal to the sum of 4s and 3d electrons. The relative stability of various oxidation states of a given element can be explained on the basis of stability of d^(0),d^(5) and d^(10) configuration . In which of the following pairs , the first species is more stable than second one

The transition element ( with few exceptions ) show a large number of oxidation states . The various oxidation states are related to the electronic configuration of their atoms. The variable oxidation states of a transition metal is due to the involvement of (n-1)d and outer ns electrons . For the first five elements of 3d transition series , the minimum oxidation state is equal to the number of electrons in 4s shell and the maximum oxidation state is equal to the sum of 4s and 3d electrons. The relative stability of various oxidation states of a given element can be explained on the basis of stability of d^(0),d^(5) and d^(10) configuration . In 3d series, the maximum oxidation state is shown by

The transition element ( with few exceptions ) show a large number of oxidation states . The various oxidation states are related to the electronic configuration of their atoms. The variable oxidation states of a transition metal is due to the involvement of (n-1)d and outer ns electrons . For the first five elements of 3d transition series , the minimum oxidation state is equal to the number of electrons in 4s shell and the maximum oxidation state is equal to the sum of 4s and 3d electrons. The relative stability of various oxidation states of a given element can be explained on the basis of stability of d^(0),d^(5) and d^(10) configuration . Identify the correct statement

NARAYNA-D BLOCK & TRANSITION ELEMENTS-Level-VI (H.W)
  1. The E^(0) values are Zn^(2+)//Zn:-0.76V,Fe^(2+)//Fe:-0.44V, Ni^(2...

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  2. The E^(0) values are Zn^(2+)//Zn:-0.76V,Fe^(2+)//Fe:-0.44V, Ni^(2...

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  3. The transition metals and their compounds have paramagnetic properties...

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  4. The transition metals and their compounds have paramagnetic properties...

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  5. The transition metals and their compounds have paramagnetic properties...

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  6. The (n-1)d shell of electron in d-block elements is expanding and, the...

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  7. The (n-1)d shell of electron in d-block elements is expanding and, the...

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  8. Paramagnetism is a property due to the presence of unpaired electrons....

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  9. Paramagnetism is a property due to the presence of unpaired electrons....

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  10. Paramagnetism is a property due to the presence of unpaired electrons....

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  11. Match the following

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  12. Match the following

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  13. S(1) : Mn^(2+) compounds more stable than Fe^(2+) towards oxidation to...

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  14. In how many of the following, the second element has a higher density ...

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  15. The number of transition metals in bronze is x, in brass is y and inGe...

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  16. Total number of 3d-series transition elements contain either 3d^(1) or...

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  17. How many of the following show variable oxidation states in their comp...

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  18. Magnetic moment value for a d-block ion is 4.90 BM determine value of ...

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  19. How many of the following ions have spin mangnetic moment more than 4...

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  20. How many of the following compounds are diamagnetic and coloured? K(...

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