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Which of the following is a tertiary alc...

Which of the following is a tertiary alcohol

A

`(CH_(3))_(2) CHCH_(2)OH`

B

`CH_(3)CH_(2)CH_(2)CH_(2)OH`

C

`CH_(3)CH_(2)CH_(2)OH`

D

`(CH_(3))_(3)COH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds is a tertiary alcohol, we need to understand the definition of tertiary alcohols and analyze each option accordingly. ### Step-by-Step Solution: 1. **Understand the Definition of Tertiary Alcohol:** A tertiary alcohol is one in which the hydroxyl (–OH) group is attached to a carbon atom that is connected to three other carbon atoms (alkyl groups). This means that the carbon atom with the –OH group has no hydrogen atoms attached to it. 2. **Analyze Each Compound:** We will look at each compound provided in the options and determine the structure to see if it fits the definition of a tertiary alcohol. - **Option 1:** CH3-CH3-CH(OH)-CH2 - The carbon with the –OH group (C) is connected to only one alkyl chain (CH2) and has two hydrogen atoms attached. This means it is a primary alcohol, not tertiary. - **Option 2:** CH3-CH2-CH2-CH2(OH) - The carbon with the –OH group is connected to only one alkyl chain (the longest chain), and it has two hydrogen atoms attached. This is also a primary alcohol. - **Option 3:** CH3-CH2-CH(OH)-CH2 - The carbon with the –OH group is connected to only one alkyl chain and has two hydrogen atoms attached. This is again a primary alcohol. - **Option 4:** CH3-CH3-CH3(OH) - The carbon with the –OH group is connected to three alkyl chains (all CH3 groups) and has no hydrogen atoms attached. This fits the definition of a tertiary alcohol. 3. **Conclusion:** Based on the analysis, the only compound that qualifies as a tertiary alcohol is **Option 4**. ### Final Answer: The tertiary alcohol among the given options is **Option 4** (CH3-CH3-CH3(OH)).
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Knowledge Check

  • Which of the following is tertiary alcohol ?

    A
    2-Methylpropan-1-ol
    B
    2-Methylpropan-2-ol
    C
    3-Methylbutan-1-ol
    D
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  • Which of the following is tertiary alcohol?

    A
    B
    C
    `CH_3-underset(CH_3)underset(|)overset(CH_3)overset(|)C-OH`
    D
    `CH_3-CH_2-OH`
  • Which of the following is tertiary alcohol

    A
    `{:(CH_(2)-OH),(|),(CH-OH),(|),(CH_(2)-OH):}`
    B
    `CH_(3)-underset(CH_(3))underset(|)underset(CH_(2))underset(|)overset(CH_(2))overset(|)(CH_(2))-CH_(2)OH`
    C
    `CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)C-OH`
    D
    `CH_(3)-CH_(2)-OH`
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