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Arrange decreasing order of reactivity o...

Arrange decreasing order of reactivity of these compounds for nucleophilic substitution reaction
(I) `CH_(3)CH_(2)-O-overset(O)overset(||)underset(O)underset(||)S-CF_(3)`
(II) `CH_(3)-CH_(2)-OTs`
(III) `CH_(3)-underset(OH)underset("| ")"CH"-OH`
(IV) `CH_(3)-underset(C_(6)H_(5))underset("| ")"CH "-OH`

A

III > IV > I > II

B

III > IV > I > II

C

I > II > III > IV

D

I > II > IV > III

Text Solution

Verified by Experts

The correct Answer is:
D
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CH_(3)-CH_(2)-CH_(2)-underset(OH)underset(|)(C )H-CH_(3) and CH_(3)-CH_(2)-underset(OH)underset(|)(C )H-CH_(2)-CH_(2)-CH_(3) are

The IUPAC name of CH_(3)-underset(OH)underset("| ")"CH"-CH_(2)-overset(CH_(3))overset("| ")underset(OH)underset("| ")"C "-CH_(3) is :

CH_(3)underset(Br)underset(|)CH-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-C-O-CH_(3)

CH_(3)-underset(CH_(3))underset(|)(CH)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH

The IUPAC name of CH_(3)-overset(OH)overset(|)underset(H)underset(|)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3) is:

The systematic name of CH_(3)-underset(O)underset(||)C-O-CH_(2)-underset(O)underset(||)C-OH

Arrange the following acid in decreasing order of their acidic strength : (I) CH_(3)-OH (II) CH_(3)CH_(2)-OH (III) CH_(3)-underset(CH_(3))underset(|)(CH)-OH (IV) CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-OH

Identify number of chiral carbons in the following compounds (I) H_(3)C-underset(OH)underset(|)(CH)-underset(OH)underset(|)(CH)-underset(OH)underset(|)(CH_(2)) (II) H_(3)-underset(CH_(3))underset(|)(CH)-underset(CH_(3))underset(|)(CH)-CH_(2)-CH_(2)

Among these chain isomers are : (I) CH_(3)-CH_(3)-CH_(2)-CH_(2)-OH (II) CH_(3)-CH_(2)-underset(OH)underset(|)(CH)-CH_(3) (III) CH_(3)-underset(CH_(3))underset(|)overset(OH)overset(|)(C)-CH_(3)

The IUPAC name of following structure is CH_(3) - overset(CH_(3)) overset(|)(CH)-underset(O)underset(||)C-CH_(2)-CH_(2)OH

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