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Calculate heat of formation of KOH(s) us...

Calculate heat of formation of `KOH(s)` using the following equations
`K(s) +H_(2)O(l) +aq rarr KOH(aq)+1//2 H_(2)(g),DeltaH =- 48.0 kcal …(i)`
`H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l),DeltaH =- 68.4 kcal …(ii)`
`KOH(s) +(aq) rarr KOH(aq),DeltaH =- 14.0 kcal ....(iii)`

A

`+102.83`

B

`+130.85`

C

`-102.83`

D

`-130.85`

Text Solution

Verified by Experts

The correct Answer is:
C
`K_((s))+1/2 O_(2) +1/2 H_(2) rarr KOH_((s)) overset(H_(2)O)(rarr) KOH_((aq))`
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Calculate heat of formation of KOH(s) using the following equations K(s) +H_(2)O(l) +aq rarr KOH(aq)+1//2 H_(2)O(g),DeltaH =- 48.0 kcal …(i) H_(2)(g) +2O_(2)(g) rarr H_(2)O(l),DeltaH =- 68.4 kcal …(ii) KOH(s) +(aq) rarr KOH(aq),DeltaH =- 14.0 kcal ....(iii)

Calculate the enthalpy of formation of KOH(s) from the following data : K(s) + H_(2)O(l) + (aq) to KOH(aq) + 1/2 H_(2)(g) Delta_(r)H^(@) = -200.8 kJ H_(2)(g) + 1/2 O_(2)(g) to H_(2)O(l) Delta_(r)H^(@) = - 286.3 kJ KOH(s) + (aq) to KOH(aq) Delta_(r)H^(@) = - 58.6 kJ

Calculate the heat of combustion of benzene form the following data: a. 6C(s) +3H_(2)(g) rarr C_(6)H_(6)(l), DeltaH = 49.0 kJ b. H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l), DeltaH =- 285.8 kJ c. C(s) +O_(2) (g) rarr CO_(2)(g), DeltaH =- 389.3 kJ

Find the heat of formation of ethyl alcohol for following data C(s) +O_(2)(g) rarr CO_(2)(g) DeltaH =- 94 kcal H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l), DeltaH =- 68 kcal C_(2)H_(5)OH(l)+3O_(2)(g) rarr 2CO_(2)(g) +3H_(2)O(l) DeltaH =- 327 kcal

Calculate the heat of formation of n butane from the followinf data: a. 2C_(4)H_(10)(g) +13O_(2)(g) rarr 8CO_(2)(g) +10H_(2)O(l), DeltaH = - 5757.2 kJ b. C(s) +O_(2) (g)rarrCO_(2)(g), DeltaH =- 405.4 kJ c. 2H_(2)(g) +O_(2)(g) rarr 2H_(2)O(l), DeltaH =- 572.4 kJ

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