Home
Class 11
CHEMISTRY
If H(2)S+3/2 O(2) rarr H(2)O+SO(2), De...

If `H_(2)S+3/2 O_(2) rarr H_(2)O+SO_(2)`,
`DeltaH=-136.7` Kcal
`H_(2)+1/2 O_(2) rarr H_(2)O, DeltaH=-68.4` Kcal
`S+O_(2) rarr SO_(2), DeltaH=-71` Kcal
What is `DeltaH_(f)` of `H_(2)S`

A

2.7 Kcal

B

`-2.7` Kcal

C

5.4 Kcal

D

`-5.4` Kcal

Text Solution

Verified by Experts

The correct Answer is:
B

`H_(2)+S rarr H_(2)S`
`DeltaH=H_(R)-H_(P)`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    NARAYNA|Exercise Level -III|64 Videos
  • THERMODYNAMICS

    NARAYNA|Exercise Level-IV|27 Videos
  • THERMODYNAMICS

    NARAYNA|Exercise Level -I (C.W)|62 Videos
  • STRUCTURE OF ATOM

    NARAYNA|Exercise EXERCISE - IV EXEMPLAR PROBLEMS|24 Videos

Similar Questions

Explore conceptually related problems

C_(2)H_(2) + 5/2 O_2(2) rarr 2CO_(2) + H_(2)O , Delta H = -310 kcal C + O_(2) rarr CO_(2) , " "Delta H = -94 kcal H_(2) + 1/2 O_(2) rarr H_(2)O, " " Delta H = -68 kcal On the basis of the above equations, DeltaH_(f) (enthalpy of formation) of C_2H_2 will be :

If {:(SO_(2)+1/2O_(2) rarr SO_(3),DeltaH = -98.7 kJ),(SO_(3)+H_2O rarr H_(2)SO_(4),DeltaH = -130.2 kJ),(H_(2)+1/2O_(2) rarr H_2O , Delta H = -287.3 kJ),(S + H_2 + 2O_(2) rarr H_2SO_4, DeltaH = -814.4 kJ):} Then enthaply of SO_(2) at 298 K is:

Statement : C+(1)/(2)O_(2) rarr CO, DeltaH=-26.0kcal CO+(1)/(2)O_(2) rarr CO_(2), DeltaH=-68.3kcal :. C+O_(2) rarr CO_(2),DeltaH=-94.3 kcal Explanation : This is an experimental proof of Hess's law.

Calculate the enthalpy of vaporisation for water form the following: H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(g),DeltaH =- 57.0 kcal H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l),DeltaH =- 68.3 kcal Also calculate the heat required to change 1g H_(2)O(l) to H_(2)O(g)

Calculate heat of formation of KOH(s) using the following equations K(s) +H_(2)O(l) +aq rarr KOH(aq)+1//2 H_(2)O(g),DeltaH =- 48.0 kcal …(i) H_(2)(g) +2O_(2)(g) rarr H_(2)O(l),DeltaH =- 68.4 kcal …(ii) KOH(s) +(aq) rarr KOH(aq),DeltaH =- 14.0 kcal ....(iii)

Given that: i. C(s) + O_(2)(g) rarr CO_(2)(g) , DeltaH =- 94.05 kcal ii. H_(2)(g) +(1)/(2) O_(2)(g) rarr H_(2)O(l), DeltaH =- 68.32 kcal iii. C_(2)H_(2)(g) +(5)/(2) O_(2)(g) rarr 2CO_(2)(g) +H_(2)O(l),DeltaH =- 310.62 kcal The heat of formation fo acetylene is

Find the heat of formation of ethyl alcohol for following data C(s) +O_(2)(g) rarr CO_(2)(g) DeltaH =- 94 kcal H_(2)(g) +1//2O_(2)(g) rarr H_(2)O(l), DeltaH =- 68 kcal C_(2)H_(5)OH(l)+3O_(2)(g) rarr 2CO_(2)(g) +3H_(2)O(l) DeltaH =- 327 kcal

Using the following thermochemical data. C(S)+O_(2)(g)rarr CO_(2)(g), Delta H=94.0 Kcal H_(2)(g)+1//2O_(2)(g)rarr H_(2)O(l), Delta H=-68.0 Kcal CH_(3)COOH(l)+2O_(2)(g)rarr 2O_(2)(g)rarr 2CO_(2)(g)+2H_(2)O(l), Delta H=-210.0 Kcal The heat of formation of acetic acid is :-

The enthalpies for the following reactions (DeltaH^(Theta)) at 25^(@)C are given below. a. (1)/(2)H_(2)(g) +(1)/(2)O_(2)(g) rarr OH(g) DeltaH = 10.06 kcal b. H_(2)(g) rarr 2H(g), DeltaH = 104.18 kcal c. O_(2)(g) rarr 2O(g), DeltaH = 118.32 kcal Calculate the O-H bond energy in the hydroxyl radical.

Using the data ( all vaues in kcal mol^(-1) at 25^(@)C) given below, calculate bond energy of C-C and C-H bonds. C_((s))rarr C_((g)), DeltaH=172 H_(2) rarr 2H, DeltaH=104 H_(2)+(1)/(2)O_(2) rarr H_(2)O_((l)), DeltaH=-68.0 C_((s))+O_(2) rarr CO_(2), Delta H=-94.0 Heat of combustion of C_(20H_(6)=-372.0 Heat of combustion of C_(3)H_(8)=-530.0

NARAYNA-THERMODYNAMICS-Level -II (C.W)
  1. The stadard heats of formation of NO(2)(g) and N(2)O(4) (g) are 33.5 a...

    Text Solution

    |

  2. The enthalpies of formation of CO(2(g)), H(2)O((l)) and C(2)H(4(g)) ar...

    Text Solution

    |

  3. If H(2)S+3/2 O(2) rarr H(2)O+SO(2), DeltaH=-136.7 Kcal H(2)+1/2 O(...

    Text Solution

    |

  4. A+3/2 O(2) rarr AO(3) = 3x KJ AO(2)+1/2 O(2) rarr AO(3) = 2y kJ Th...

    Text Solution

    |

  5. The enthalpy change during the formation of 24.95 grams of hydrated co...

    Text Solution

    |

  6. The molar enthalpies of combustion of C(2)H(2)(g), C("graphite") and H...

    Text Solution

    |

  7. For a given reaction, C(7)H(8(l))+9I(2) (g) rarr 7CO(2)(g) +4H(2)O(l...

    Text Solution

    |

  8. Hess's law states that

    Text Solution

    |

  9. Heat of reaction (DeltaH) is given by

    Text Solution

    |

  10. The values of the combustion of graphite and H(2) are -395 and -269 kJ...

    Text Solution

    |

  11. The heat of combustion of sucrose C(12) H(22) O(11)(s) at constant vol...

    Text Solution

    |

  12. At 298 K, the heat of solution of MgSO(4) (s) is -91.21 kJ mol^(-1) an...

    Text Solution

    |

  13. The entropy change for cooling 1.6 g of an organic compound (mol. Wt. ...

    Text Solution

    |

  14. The entropy change during heating of 50 g water (sp. Heat =4200 J kg^(...

    Text Solution

    |

  15. Standard molar entropies of Mg((s)), C((s)), MgO((s)) & CO((g)) respec...

    Text Solution

    |

  16. The value DeltaS for the process H(2)O(s) rarr H(2)O(l) at 1 atm pre...

    Text Solution

    |

  17. On the basis of information available from the reaction (4)/(3)Al+O(...

    Text Solution

    |

  18. Consider the following reactions at 1000^(@)C. (A) Zn((s))+1/2 O(2(g...

    Text Solution

    |

  19. Acetic acid forms dimer in vapour phase. The dimer is held together by...

    Text Solution

    |

  20. The temperature in K at which DeltaG=0 for a given reaction with Delta...

    Text Solution

    |