Home
Class 11
CHEMISTRY
In a fuel cell methanol is used as fuel ...

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is `:`
`CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_2((g))+2H_(2)O_((l))`
At `298K` standard Gibb's energies of formation for `CH_(3)OH(l), H_(2)O(l)` and `CO_(2)(g)` are `-166.2,-237.2` and `-394.4kJ mol^(-1)` respectively. If standard enthalpy of combustion of methanol is `-726kJ mol^(-1)`, efficiency of the fuel cell will be `:`

A

`80%`

B

`87%`

C

`90%`

D

`97%`

Text Solution

Verified by Experts

The correct Answer is:
D

`DeltaG=G_(P)-G_(R)`, Efficiency of fuelcell `= (DeltaG)/(DeltaH)xx100`
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    NARAYNA|Exercise Level-IV|27 Videos
  • THERMODYNAMICS

    NARAYNA|Exercise Level -I (H.W)|38 Videos
  • THERMODYNAMICS

    NARAYNA|Exercise Level -II (C.W)|41 Videos
  • STRUCTURE OF ATOM

    NARAYNA|Exercise EXERCISE - IV EXEMPLAR PROBLEMS|24 Videos

Similar Questions

Explore conceptually related problems

In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is : CH_(3)OH_((l))+(3)/(2)O_(2(g))rarr CO_((g))+2H_(2)O_((l)) At 298K standard Gibb's energies of formation for CH_(3)OH(l), H_(2)O(l) and CO_(2)(g) are -166.2,-237.2 and -394.4kJ mol^(-1) respectively. If standard enthalpy of combustion of methanol is -726kJ mol^(-1) , efficiency of the fuel cell will be :

In a fuel cell, methanol if used as fuel and oxygen gas is used as an oxidiser. The reaction is CH_(3)OH(l) +(3)/(2)O_(2)(g)rarrCO_(2)(g)+2H_(2)O(l) Calculated standard Gibbs free enegry change for the reaction that can be converted into electircal work. If standard enthalpy of combustion for methanol is -702 kJ mol^(-1) , calculate the efficiency of converstion of Gibbs energy into useful work. Delta_(f)G^(Theta) for CO_(2),H_(2)O, CH_(3)OH,O_(2) is -394.00, -237.00,-166.00 and 0 kJ mol^(-1) respectively.

The heat of formations for CO_(2)(g),H_(2)O(l) and CH_(4)(g) are -400 kJ mol^(-1),-280" kJ "mol^(-1) and -70" kJ "mol^(-1) , respectively. The heat of combustion of CH_(4) in kJ mol^(-1) is

In a fuel celll, methanol is used as a fuel and O_(2) is used as oxidizer. The standard enthalpy of combustion of methanol is -726 kJ mol^(-1) . The standard free energies of formation of CH_(3)OH(I), CO_(2)(g) and H_(2)O(I) are -166.3, -394.4 and -237.1 kJ mol^(-1) respectively. The standard free energy change of the reaction will be

NARAYNA-THERMODYNAMICS-Level -III
  1. The molar heat capacity (C(P)) of CD(2)O is 10 cals at 1000 K. The cha...

    Text Solution

    |

  2. At 60^(@)C, dinitrogen tetroxide is 50 per cent dissociated. Calculate...

    Text Solution

    |

  3. For a spontaneous reaction the DeltaG, equilibrium constant (K) and E(...

    Text Solution

    |

  4. Identify the correct statement regarding a spontaneous process.

    Text Solution

    |

  5. The standard Gibb's energy change for the formation of propane. C(3)H(...

    Text Solution

    |

  6. Which of the following expression defines the physical significance of...

    Text Solution

    |

  7. The incorrect expression among the following is

    Text Solution

    |

  8. For a particular reversible reaciton at temperature T, DeltaH and Delt...

    Text Solution

    |

  9. In a fuel cell methanol is used as fuel and oxygen gas is used as an o...

    Text Solution

    |

  10. On the basis of the following thermochemical data : (Delta(f)G^(@)H((a...

    Text Solution

    |

  11. In view of the signs of Delta(r)G^(0) for the following reactions Pb...

    Text Solution

    |

  12. The value of enthalpy change (DeltaH) for the reaction C(2)H(5)OH (l...

    Text Solution

    |

  13. Consider the reaction, 4NO(2)(g)+O(2)(g)rarr2N(2)O(5)(g),Delta(r )H=...

    Text Solution

    |

  14. For the complete combustion of ethanol, C(2)H(5)OH(l)+3O(2)(g)rarr2CO(...

    Text Solution

    |

  15. The standed free energy of fromation of NO(g) is 86.6 kj/ mol at 298...

    Text Solution

    |

  16. If 100 mole of H(2)O(2) decompose at 1 bar and 300 K, the work done (k...

    Text Solution

    |

  17. For the reaction, A(g)+B(g) rarr C(g)+D(g), DeltaH^(@) and DeltaS^(@...

    Text Solution

    |

  18. A reaction at 1 bar is non-spontaneous at low temperature but becomes ...

    Text Solution

    |

  19. one mole of an ideal gas at 300k in thermal contact with surroundings ...

    Text Solution

    |

  20. The enthalpies of combustion of carbon and carbon monoxide are -393.5 ...

    Text Solution

    |