Home
Class 11
CHEMISTRY
A reaction at 1 bar is non-spontaneous a...

A reaction at 1 bar is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following:

A

Both `DeltaH` and `DeltaS` are positive

B

`DeltaH` is negative while `DeltaS` is positive

C

`DeltaH` is positive while `DeltaS` is positive

D

Both `DeltaH` and `DeltaS` are negative

Text Solution

Verified by Experts

The correct Answer is:
A

`DeltaG = DeltaH - T. DeltaS`
If `DeltaH` & `Delta S` are both positive, then `DeltaG` may be negative at height temperature hence reaction becomes spontaneous at higher temperature.
Promotional Banner

Topper's Solved these Questions

  • THERMODYNAMICS

    NARAYNA|Exercise Level-IV|27 Videos
  • THERMODYNAMICS

    NARAYNA|Exercise Level -I (H.W)|38 Videos
  • THERMODYNAMICS

    NARAYNA|Exercise Level -II (C.W)|41 Videos
  • STRUCTURE OF ATOM

    NARAYNA|Exercise EXERCISE - IV EXEMPLAR PROBLEMS|24 Videos

Similar Questions

Explore conceptually related problems

A reaction is spontaneous at low temperature but non- spontaneous at high temperature. Which of the following is true for the reaction?

A reaction is non-spontaneous when:

The a reaction to be spontaneous at all temperature

An endothermic process is non-spontaneous at some temperature. It can be spontaneous at………….temperature.

Which of the reaction is expectd to be spontaneous at low temperatures and non-spontaneous at high temperatures:

Identify the correct statement regarding a spontaneous process:

NARAYNA-THERMODYNAMICS-Level -III
  1. The molar heat capacity (C(P)) of CD(2)O is 10 cals at 1000 K. The cha...

    Text Solution

    |

  2. At 60^(@)C, dinitrogen tetroxide is 50 per cent dissociated. Calculate...

    Text Solution

    |

  3. For a spontaneous reaction the DeltaG, equilibrium constant (K) and E(...

    Text Solution

    |

  4. Identify the correct statement regarding a spontaneous process.

    Text Solution

    |

  5. The standard Gibb's energy change for the formation of propane. C(3)H(...

    Text Solution

    |

  6. Which of the following expression defines the physical significance of...

    Text Solution

    |

  7. The incorrect expression among the following is

    Text Solution

    |

  8. For a particular reversible reaciton at temperature T, DeltaH and Delt...

    Text Solution

    |

  9. In a fuel cell methanol is used as fuel and oxygen gas is used as an o...

    Text Solution

    |

  10. On the basis of the following thermochemical data : (Delta(f)G^(@)H((a...

    Text Solution

    |

  11. In view of the signs of Delta(r)G^(0) for the following reactions Pb...

    Text Solution

    |

  12. The value of enthalpy change (DeltaH) for the reaction C(2)H(5)OH (l...

    Text Solution

    |

  13. Consider the reaction, 4NO(2)(g)+O(2)(g)rarr2N(2)O(5)(g),Delta(r )H=...

    Text Solution

    |

  14. For the complete combustion of ethanol, C(2)H(5)OH(l)+3O(2)(g)rarr2CO(...

    Text Solution

    |

  15. The standed free energy of fromation of NO(g) is 86.6 kj/ mol at 298...

    Text Solution

    |

  16. If 100 mole of H(2)O(2) decompose at 1 bar and 300 K, the work done (k...

    Text Solution

    |

  17. For the reaction, A(g)+B(g) rarr C(g)+D(g), DeltaH^(@) and DeltaS^(@...

    Text Solution

    |

  18. A reaction at 1 bar is non-spontaneous at low temperature but becomes ...

    Text Solution

    |

  19. one mole of an ideal gas at 300k in thermal contact with surroundings ...

    Text Solution

    |

  20. The enthalpies of combustion of carbon and carbon monoxide are -393.5 ...

    Text Solution

    |