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The total number of optically active iso...

The total number of optically active isomers for `CH_(2)OH(CHOH)_(3)CHO` are

A

16

B

8

C

4

D

2

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The correct Answer is:
To determine the total number of optically active isomers for the compound CH₂OH(CHOH)₃CHO, we need to follow these steps: ### Step 1: Identify the Structure The compound can be represented as: - CH₂OH (a hydroxymethyl group) - (CHOH)₃ (three hydroxymethyl groups attached to a carbon chain) - CHO (an aldehyde group) ### Step 2: Identify Chiral Centers A chiral center is a carbon atom that is bonded to four different groups. In the given compound, we need to analyze each carbon atom to determine if it is chiral. 1. **First Carbon (C1)**: CH₂OH - This carbon has two hydrogen atoms, so it is **not chiral**. 2. **Second Carbon (C2)**: CHOH - This carbon is bonded to: - OH (hydroxyl group) - H (hydrogen) - CH₂OH (hydroxymethyl group) - CHO (aldehyde group) This carbon is **chiral**. 3. **Third Carbon (C3)**: CHOH - Similar to C2, this carbon is bonded to: - OH (hydroxyl group) - H (hydrogen) - CH₂OH (hydroxymethyl group) - Another CHOH (from the next carbon) This carbon is also **chiral**. 4. **Fourth Carbon (C4)**: CHO - This carbon is part of the aldehyde group and is bonded to: - O (from the carbonyl) - H (hydrogen) - CHOH (from the previous carbon) - CH₂OH (from the first carbon) This carbon is **not chiral**. ### Step 3: Count the Chiral Centers From the analysis, we find that there are **two chiral centers** (C2 and C3). ### Step 4: Calculate the Number of Optically Active Isomers The formula to calculate the number of optically active isomers based on the number of chiral centers (n) is given by: \[ \text{Number of isomers} = 2^n \] Where n is the number of chiral centers. In our case, we have: \[ n = 2 \] Thus, the number of optically active isomers is: \[ 2^2 = 4 \] ### Conclusion The total number of optically active isomers for CH₂OH(CHOH)₃CHO is **4**. ---

To determine the total number of optically active isomers for the compound CH₂OH(CHOH)₃CHO, we need to follow these steps: ### Step 1: Identify the Structure The compound can be represented as: - CH₂OH (a hydroxymethyl group) - (CHOH)₃ (three hydroxymethyl groups attached to a carbon chain) - CHO (an aldehyde group) ...
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NARAYNA-GENERAL ORGANIC CHEMISTRY-Optical Isomerism:
  1. Optical inactivity of meso isomers is due to

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  2. The 'd' and 'l' forms of an optically active compound differ in

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  3. A recemic mixture is a mixture of

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  4. d-tartaric acid and l-tartric acid are

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  5. Meso isomers are possible when the organic compound contains

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  6. Meso-tartaric acid is optically inactive due to the presence of

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  7. Optically active isomers but not mirror images are callled

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  8. IUPAC name of the compound

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  9. A racemic mixtrue is optically inactive due to :

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  10. The process of separating a racemic mixture into optically pure (+) an...

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  11. d-tartaric acid and l-tartric acid can be seperated by

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  12. A similarity between optical and geometrical isomerism is that

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  13. Optically active tartaric acid is named as D(+) tartaric acid because ...

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  14. Wrong statement among the following

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  15. Which of the following compounds is not chiral

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  16. Minimum numbe of C atoms for an alkene hydrocarbon, that shows geometr...

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  17. The number of asymmetric carbons and number of optical isomers the com...

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  18. The total number of optically active isomers for CH(2)OH(CHOH)(3)CHO a...

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  19. Amongst the following compounds, the optically active alkane having lo...

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  20. The structure Shows

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