Home
Class 11
CHEMISTRY
Which of the Newman projections shown be...

Which of the Newman projections shown below represents the most stable conformation about the `C_(1)-C_(2)` bond of 1-iodo-2-methyl propance?

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which Newman projection represents the most stable conformation about the C1-C2 bond of 1-iodo-2-methylpropane, we can follow these steps: ### Step 1: Draw the Structure of 1-Iodo-2-methylpropane 1. Identify the structure of 1-iodo-2-methylpropane: - The main chain is propane (3 carbon atoms). - The first carbon (C1) has an iodine (I) substituent. - The second carbon (C2) has a methyl (CH3) substituent. - The third carbon (C3) has two hydrogen atoms (H). The structure can be represented as: ``` CH3 | H3C - C - CH2 - I | H ``` ### Step 2: Identify the Newman Projections 2. Analyze the given Newman projections: - Each projection represents the conformation of the molecule when looking down the C1-C2 bond. - We need to evaluate the steric interactions in each projection. ### Step 3: Evaluate Steric Hindrance 3. For each Newman projection, assess the steric hindrance: - **Staggered Conformation**: This is generally more stable as it minimizes steric hindrance between bulky groups. - **Eclipsed Conformation**: This is less stable due to increased steric hindrance as groups are aligned with each other. ### Step 4: Compare the Projections 4. Compare the four projections: - **Projection A**: Check for steric hindrance; if there are bulky groups eclipsing each other, this is less stable. - **Projection B**: Similar evaluation; look for eclipsing interactions. - **Projection C**: If this shows a staggered conformation with minimal hindrance, it may be more stable. - **Projection D**: Again, check for steric hindrance. ### Step 5: Determine the Most Stable Conformation 5. Identify the most stable conformation: - After analyzing all projections, the one with the least steric hindrance and in a staggered arrangement will be the most stable. - Based on the analysis, **Projection C** is determined to be the most stable conformation due to its staggered arrangement, minimizing steric interactions. ### Conclusion The most stable conformation about the C1-C2 bond of 1-iodo-2-methylpropane is represented by **Projection C**. ---

To determine which Newman projection represents the most stable conformation about the C1-C2 bond of 1-iodo-2-methylpropane, we can follow these steps: ### Step 1: Draw the Structure of 1-Iodo-2-methylpropane 1. Identify the structure of 1-iodo-2-methylpropane: - The main chain is propane (3 carbon atoms). - The first carbon (C1) has an iodine (I) substituent. - The second carbon (C2) has a methyl (CH3) substituent. - The third carbon (C3) has two hydrogen atoms (H). ...
Promotional Banner

Topper's Solved these Questions

  • ISOMERISM

    GRB PUBLICATION|Exercise REASONING TYPE|24 Videos
  • ISOMERISM

    GRB PUBLICATION|Exercise MULTIPLE OBJECTIVE TYPE|71 Videos
  • GASEOUS STATE

    GRB PUBLICATION|Exercise Exercise|530 Videos
  • MOLE CONCEPT, STOICHIOMETRY & CONCENTRATION TERMS

    GRB PUBLICATION|Exercise Subjective type|145 Videos

Similar Questions

Explore conceptually related problems

Which of the following represents the most stable conformation of 5-hydroxy -1,3-dioxane?

C_(1)-C_(2) bond is shortest in :

Which is the most stable conformer along the 2, 3 C-C bond axis of the compound ?

The most stable conformational isomer of trans-1-ethyl-2-methylcyclohexane will be

Which is most stable conformer of ethan-1,2-diol

Write Gauche conformation of the compound CH_(2) C1 -CH_(2) C1

GRB PUBLICATION-ISOMERISM-SUBJECTIVE TYPE
  1. Which of the Newman projections shown below represents the most stable...

    Text Solution

    |

  2. Total nubler of mono chlorodervatives obrained by replacement of H by ...

    Text Solution

    |

  3. Calculate valur of x+y+z+if xto Number of chiral centre. yto Numb...

    Text Solution

    |

  4. Tetracyline is called a broad spectrum antibiontic because it active a...

    Text Solution

    |

  5. How many stereoismers are possible for the following compound?

    Text Solution

    |

  6. What will be the number of hydrogen atoms (Y) replaced by D on prolong...

    Text Solution

    |

  7. underset(hv)overset(Cl(2))rarr number of theretically possible dichlor...

    Text Solution

    |

  8. Total number of stereoisomer in given compound are : CH(3)-overset(O...

    Text Solution

    |

  9. Cyclohexane-4,4-idone is a polar compound, having dipole moment value ...

    Text Solution

    |

  10. How many H are replaced by D on prolonged treament in the following? ...

    Text Solution

    |

  11. Number of chiral centres present in above compound. Number of teoret...

    Text Solution

    |

  12. When 20 gm optically active compound is placed in a 10 dm tube, in a 2...

    Text Solution

    |

  13. How many plane of symmetry are present in cyclopropane?

    Text Solution

    |

  14. How many chiral carbon atoms are present in the following compound?

    Text Solution

    |

  15. How many plane of symmetry are present in prismane (C(6)H(6))?

    Text Solution

    |

  16. An unknown compound weighin 4.2 gm is dissolved in enotgh carbon tetra...

    Text Solution

    |

  17. How many compounds are theretically possible for formula (C(6)H(6)O) (...

    Text Solution

    |

  18. How many of the following are resolvable ?

    Text Solution

    |

  19. How many total number of structural isomers are possible for C(4)H(7)C...

    Text Solution

    |

  20. How many total number of structural isomers of C(4)H(6)Cl(2) are possi...

    Text Solution

    |

  21. Dipole moment of a compound W-CH(2)-CH(2)-W is 1.5 D.if dipole moment ...

    Text Solution

    |