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Which of the following compound will sho...

Which of the following compound will show tautomerism?

A

B

`Me_3C--C-=N`

C

D

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The correct Answer is:
To determine which of the given compounds will show tautomerism, we need to understand the concept of tautomerism and analyze each compound based on the presence of alpha-hydrogens and the ability to form enol forms. ### Step-by-Step Solution: 1. **Understanding Tautomerism**: - Tautomerism is a type of isomerism where two isomers, called tautomers, can readily interconvert. This typically involves the relocation of a hydrogen atom and a shift of a double bond. The most common example is the keto-enol tautomerism, where a ketone (or aldehyde) can convert to its corresponding enol form. 2. **Identifying Alpha-Hydrogens**: - For a compound to exhibit tautomerism, it must have at least one alpha-hydrogen (a hydrogen atom attached to the carbon adjacent to the carbonyl carbon). The presence of this hydrogen is crucial for the tautomerization process. 3. **Analyzing Each Compound**: - **Compound A**: - Structure: Contains a carbonyl group (C=O) and has alpha-hydrogens available for removal. - Conclusion: This compound can undergo tautomerism. - **Compound B**: - Structure: Contains a carbon with a triple bond and no alpha-hydrogens. - Conclusion: This compound cannot undergo tautomerism due to the absence of alpha-hydrogens. - **Compound C**: - Structure: A bicyclic compound with a carbonyl group and limited alpha-hydrogens. - Conclusion: Although it has one alpha-hydrogen, the non-planarity of the structure prevents it from effectively undergoing tautomerism. - **Compound D**: - Structure: Similar to compound A but lacks conjugation and has no effective way to stabilize the enol form. - Conclusion: This compound cannot undergo tautomerism due to the lack of conjugation and instability of the enol form. 4. **Final Conclusion**: - The only compound that shows tautomerism is **Compound A**. ### Answer: The compound that will show tautomerism is **Compound A**.

To determine which of the given compounds will show tautomerism, we need to understand the concept of tautomerism and analyze each compound based on the presence of alpha-hydrogens and the ability to form enol forms. ### Step-by-Step Solution: 1. **Understanding Tautomerism**: - Tautomerism is a type of isomerism where two isomers, called tautomers, can readily interconvert. This typically involves the relocation of a hydrogen atom and a shift of a double bond. The most common example is the keto-enol tautomerism, where a ketone (or aldehyde) can convert to its corresponding enol form. 2. **Identifying Alpha-Hydrogens**: ...
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