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Ethyl acetoacetate when reacts with one ...

Ethyl acetoacetate when reacts with one mole methyl magnesium iodide then product of reaction will be :

A

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)`

B

`CH_(3)-underset(CH_(3))underset(|)overset(O^(Θ)Mg^(o+)Br)overset(|)(C)-CH_(2)-overset(O)overset(||)(C)-CH_(3)`

C

`CH_(3)-overset(O)overset(||)(C)-underset(overset(o+)(MgBr))overset(Θ)(CH)-CO_(2)Et`

D

`CH_(2)^(-)overset(O)overset(||)(C)-CH_(2)-CO_(2)Et`

Text Solution

Verified by Experts

The correct Answer is:
C

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-overset(O)overset(||)(C)-O-Et overset(CH_(3)MgBr)rarrCH_(3)-overset(O)overset(||)(C)-underset(overset(o+)(MgBr))overset(Θ)(CH)-CO_(2)Et`
(because of active methylene group acid-base take place).
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