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The periodicity is related to the electr...

The periodicity is related to the electronic configuration. That is, all chemical and phyical properties are a manifestation of the electronic configurfation of the elements.
The atomic and ionic radii generally decrease in a preiod from left or right. As a consequence , the ionisation enthalpies generally increase and electron gain enthalpies become more negative across a period. In other words, the ionisation enthalpy of the extreme left element in a period is the least and the electron left element on the extreme right is the highest negative. This results into high chemical reactivity at two extgremes and the lowest in the centre. Similarly down the group, the increase in atomic and ionic radii result in gradual decrease (with excetption in some third period elements) in electron gain enthalpies in the case of main group elements .
These properties can be related with the
(i) reducing and oxidising behacviour of the elements
(ii) metallic and no-metallic charcter of element
(iii) acidic, basic , amphoteric and neutral character of the oxides of the elements.
Which of the following statement is incorrect?

A

In general metallic character increases down the group and decrease across a period.

B

In general reducing property decreases down the group and increases across a period.

C

In general, the oxide formed by the element on extreme right of the periodic table is the most acidic.

D

Chemical reactivity of non-metals in terms of oxidisong power increases from nitrogen to fluroine across the period.

Text Solution

Verified by Experts

The correct Answer is:
B
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  7. According to I.C slater effective nuclear charge, Z^(**), due to scree...

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  9. The first four successive ionization energies for an element are 6 , 1...

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  10. The number of species among the following , having insert gas configu...

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  11. The number of elements among the following atomic numbers that are p b...

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  12. Among the following oxides, how many of them are amphoteric oxides? ...

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  13. The no. of elements which are more electropositive than 'Fe' in the f...

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  14. The no. of paramagnetic species in the following . Na^(+),Cl^(-), Sn^(...

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  15. 1.0 g of Mg atom ("atomic mass" = 24.0 "amu") in the vapour phase abso...

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  16. The ionisation energy of Li is 500 KJ/mole. The amount of energy requi...

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  17. The first IP lithium is 5.41eV and electron gain enthalpy of Cl is -3....

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