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Conductance of 0.1 M KCl (conductiviy = ...

Conductance of `0.1` M KCl (conductiviy = `X ohm^(-1) cm^(-1)`) filled in a conductivity cell is Y `ohm^(-1)` If the conductance of 0.1 M NaOH filled in the same cell is Z `ohm^(-1)` the molar conductance of NaOH will be

A

`10^(3)(XZ)/Y`

B

`10^(4) (XZ)/Y`

C

`10(XZ)/Y`

D

`0.1(XZ)/Y`

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The correct Answer is:
To find the molar conductance of NaOH using the information given about KCl and NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the relationship between conductivity, conductance, and cell constant:** \[ \text{Conductivity} (k) = \text{Conductance} (G) \times \text{Cell Constant} (C) \] Here, the conductivity of KCl is given as \( x \, \text{ohm}^{-1} \text{cm}^{-1} \) and the conductance is given as \( Y \, \text{ohm}^{-1} \). 2. **Calculate the cell constant (C) using KCl data:** \[ C = \frac{k}{G} = \frac{x}{Y} \] 3. **Determine the conductivity of NaOH using its conductance:** The conductance of 0.1 M NaOH is given as \( Z \, \text{ohm}^{-1} \). Using the same cell constant, we can express the conductivity of NaOH as: \[ k_{\text{NaOH}} = Z \times C = Z \times \frac{x}{Y} \] 4. **Use the formula for molar conductance (Λ):** Molar conductance is given by: \[ \Lambda = \frac{k \times 1000}{\text{Molarity}} \] For NaOH, the molarity is \( 0.1 \, \text{M} \): \[ \Lambda_{\text{NaOH}} = \frac{k_{\text{NaOH}} \times 1000}{0.1} \] 5. **Substituting the expression for \( k_{\text{NaOH}} \):** \[ \Lambda_{\text{NaOH}} = \frac{(Z \times \frac{x}{Y}) \times 1000}{0.1} \] 6. **Simplifying the expression:** \[ \Lambda_{\text{NaOH}} = \frac{Z \times x \times 1000}{0.1 \times Y} = \frac{Z \times x \times 10000}{Y} \] ### Final Expression: Thus, the molar conductance of NaOH is given by: \[ \Lambda_{\text{NaOH}} = \frac{Z \times x \times 10000}{Y} \]

To find the molar conductance of NaOH using the information given about KCl and NaOH, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the relationship between conductivity, conductance, and cell constant:** \[ \text{Conductivity} (k) = \text{Conductance} (G) \times \text{Cell Constant} (C) \] ...
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