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For the same metal, the stabiliing energ...

For the same metal, the stabiliing energies of tetrahedral and octahedral complex are related as

A

`Delta_(t) = Delta_(0)`

B

`Delta_(t)xx4 = Delta_(0)xx6`

C

`Delta_(t)xx9 = Delta_(0)xx4`

D

`Delta_(t)xx6 = Delta_(0)xx4`

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The correct Answer is:
To find the relationship between the stabilizing energies of tetrahedral and octahedral complexes for the same metal, we can follow these steps: ### Step 1: Understand the Definitions - **Tetrahedral Complex**: A coordination complex where the central metal atom is surrounded by four ligands. - **Octahedral Complex**: A coordination complex where the central metal atom is surrounded by six ligands. - **Stabilizing Energy**: The energy associated with the formation of the complex, often denoted as Δt for tetrahedral and Δo for octahedral complexes. ### Step 2: Compare Stabilizing Energies It is known that the stabilizing energy of octahedral complexes is generally greater than that of tetrahedral complexes. This can be expressed as: \[ \Delta o > \Delta t \] ### Step 3: Establish the Relationship The relationship between the stabilizing energies of tetrahedral and octahedral complexes can be derived from crystal field theory. It is established that: \[ \Delta t = \frac{4}{9} \Delta o \] This means that the stabilizing energy of a tetrahedral complex is \( \frac{4}{9} \) of that of an octahedral complex. ### Step 4: Rearranging the Equation To express this relationship in a different form, we can rearrange the equation: \[ \Delta t \times 9 = 4 \times \Delta o \] ### Step 5: Conclusion Thus, we conclude that the relationship between the stabilizing energies of tetrahedral and octahedral complexes for the same metal is: \[ \Delta t \times 9 = 4 \times \Delta o \] ### Final Answer The correct relationship is given by the equation: \[ \Delta t \times 9 = 4 \times \Delta o \]

To find the relationship between the stabilizing energies of tetrahedral and octahedral complexes for the same metal, we can follow these steps: ### Step 1: Understand the Definitions - **Tetrahedral Complex**: A coordination complex where the central metal atom is surrounded by four ligands. - **Octahedral Complex**: A coordination complex where the central metal atom is surrounded by six ligands. - **Stabilizing Energy**: The energy associated with the formation of the complex, often denoted as Δt for tetrahedral and Δo for octahedral complexes. ### Step 2: Compare Stabilizing Energies ...
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