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In the complex with formula MCl(3).4H(2)...

In the complex with formula `MCl_(3).4H_(2)O` the co-ordination number of the metal M is six. And there is a no molecule of hydration in it. The volume of 0.1 M `AgNO_(3)` solution needed to precitate the free chloride ions in 200 ml of 0.01 M solution of the complex is

A

40 ml

B

20 ml

C

60 ml

D

80 ml

Text Solution

Verified by Experts

The correct Answer is:
2
Formula of complex is `[MCl(H_(2)O)_(4)]Cl`. Ionisable `Cl^(-)` atoms are only one. `M_(1)V_(1) =M_(2)V_(2), Vxx0.1 = 200X0.1`
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NARAYNA-COORDINATION COMPLEXES-LEVEL-III
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