Home
Class 12
CHEMISTRY
The magnetic moment of [Ni(Cl)(4)]^(2-) ...

The magnetic moment of `[Ni(Cl)_(4)]^(2-)` is

A

Statement-1 is true,Statement-2 is True, Statement-2 is a correct explanation for Statement-2

B

Statement- is True, Statement-2 is True, Statement-2 is not a correct explanantion for Statement-2

C

Statement-1 is True,Statement-2 is False

D

Statement-1 is False, Statement-2 is True.

Text Solution

Verified by Experts

The correct Answer is:
D

`Delta_(0)Pt^(2+) gt Delta_(0)Ni^(2+)` , The `Cl^(-)` ligand could pair up `e^(-)` in 5d orbitals but could not pair up `e^(-)` in 3d orbitals . 5d orbitals are more open and diffused than 3d orbitals.
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPLEXES

    NARAYNA|Exercise Integer Type Questions|54 Videos
  • COORDINATION COMPLEXES

    NARAYNA|Exercise FILL IN THE BLANKS|6 Videos
  • COORDINATION COMPLEXES

    NARAYNA|Exercise Matrix Matching Questions|19 Videos
  • CO-ORDINATE COMPOUNDS

    NARAYNA|Exercise Exercise-4|60 Videos
  • D - BLOCK ELEMENTS

    NARAYNA|Exercise CHECK YOUR GRASP|7 Videos

Similar Questions

Explore conceptually related problems

Spin only magnetic moment of [PtCl_4]^(2-) is

Transition metals and many of their compounds show paramagnetic behaviour where there are unpaired electron or electrons. The magnetic moment arises from the spin and orbital motions in ions or molecule. Magnetic moment of n unpaired electrons is given as mu=sqrt(n(n+2)) Bohr magneton Magnetic moment increases as the number of unpaired electrons increases. Q. Magnetic moment of [Ni(CN)_4]^(2-) is zero but that of [Ni(H_2O)_4]^(2+) is 2.83BM . is because of :

Define ligand. Explain the magnetic properties of [Ni(CN)_(4)]^(2-)

The magnetic moment (spin only) of [NiCl_4]^(2+) is

The magnetic moment (spin only) of [NiCl_(4)]^(2-) is