Home
Class 12
CHEMISTRY
In group separation, before precipitatin...

In group separation, before precipitating out group III metal ions as hydroxides, it is necessary to boil then solution of the salt mixture with a few drops of concentrated `HNO_(3)` is treated. This is done to convert:

A

`Co^(2+)` to `Co^(3+)`

B

`Fe^(2+)` to `Fe^(3+)`

C

`Mn^(2+)` to `MnO_(4)^(-)`

D

`Cr^(3+)` to `CrO_(4)^(2-)`

Text Solution

Verified by Experts

The correct Answer is:
B

This is usually done ot convert `Fe^(2+)` to `Fe^(3+)` because `Fe^(III)` hydroxides are insoluble which can be separated to a large extent from more soluble than `Fe^(II)` hydroxides.
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS

    NARAYNA|Exercise Comprehension Type (Passage -I)|7 Videos
  • QUALITATIVE ANALYSIS

    NARAYNA|Exercise Passage -II|7 Videos
  • QUALITATIVE ANALYSIS

    NARAYNA|Exercise Integer Type Questions|11 Videos
  • PRACTICAL ORGANIC CHEMISTRY

    NARAYNA|Exercise SUBJECTIVE_TYPE|1 Videos
  • SOLID STATES

    NARAYNA|Exercise EXERCISE-4|18 Videos

Similar Questions

Explore conceptually related problems

Before adding the reagents of group III, the solution is heated with some concentrated HNO_(3) in order to :

A white crystalline substance dissolves in water.On passing H_(2)S in this solution, a black precipitate is obtained.The black precipitate dissolves completely in hot HNO_(3) .On adding a few drops of concentrated H_(2)SO_(4) , a white precipitate is obtained.This precipitate is that of

Which salt precipitates as metal hydroxide on reaction with Na_(2)CO_(3) solution.

NARAYNA-QUALITATIVE ANALYSIS-Level -VI
  1. When measured amount of CN^(-) is added to a solution of Cu^(2+) ions ...

    Text Solution

    |

  2. Which of the following statements is incorrect ?

    Text Solution

    |

  3. In group separation, before precipitating out group III metal ions as ...

    Text Solution

    |

  4. AgNO(3) solution produces white ppt. with a solution (A) which turns ...

    Text Solution

    |

  5. Some of the following statements are correct and some are incorrect. ...

    Text Solution

    |

  6. For the precipitation group IV metal ions as their insoluble carbonate...

    Text Solution

    |

  7. A salt mixture contains anions A^(-) & B^(-) . To the sodium carbonate...

    Text Solution

    |

  8. Which of the following statement is incorrect.

    Text Solution

    |

  9. Aqueous ZnSO(4) treated with Na(2)CO(3)//H(2)O produces A which when h...

    Text Solution

    |

  10. Which the following nitrate does not perform brown ring test ?

    Text Solution

    |

  11. Which of the following will not give positive chromyl chloride test?

    Text Solution

    |

  12. A metal gives two chlorides 'A' and 'B'.'A' gives black precipitate wi...

    Text Solution

    |

  13. The missing product in the reaction Mg^(2+)+HPO(4)^(2-)+NH(4)OH rarr...

    Text Solution

    |

  14. A metal salt solution forms a yellow precipitate with potassium chroma...

    Text Solution

    |

  15. Some pale-green crystals are strongly heated. The gases give off are p...

    Text Solution

    |

  16. An aqueous solutio of a salt (A) gives white precipitate with NaCl sol...

    Text Solution

    |

  17. A white powder when strongly heated gives of brown fumes. A solution o...

    Text Solution

    |

  18. A reddish pink substance on heating gives off a vapour which condenses...

    Text Solution

    |

  19. When two colourless solutions are mixed, it results a white precipitat...

    Text Solution

    |

  20. An acidic solution of 'X' does not give percipitate on passing H(2)S t...

    Text Solution

    |