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A solution of a salt gives a precipitate...

A solution of a salt gives a precipitate on treatment with dilute HCl. The precipitate formed is filtered off and treated with `NH_(3)` whereby it turns black. The cation present in the salt is

A

`Ag^(+)`

B

`Hg^(2+)`

C

`Hg_(2)^(2+)` and `Cd^(2+)`

D

`Pb^(2+)`

Text Solution

Verified by Experts

The correct Answer is:
C

`Hg_(2)^(2+)+HClrarrunderset(darr NH_(3))(Hg_(2)Cl_(2)darr)("white ppt")`
`Hg^(-)("Black")+Hg(NH_(2))Cl`
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