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Given : C("diamond")+O(2)rarrCO(2),De...

Given :
`C("diamond")+O_(2)rarrCO_(2),DeltaH=-395 kJ`
`C("graphite")+O_(2)rarrCO_(2),DeltaH=-393 kJ`
The enthalpy of formation of diamond from graphite is

A

`+ 2.0 kJ`

B

`-1.5 kJ`

C

`-788 kJ`

D

788 kJ

Text Solution

AI Generated Solution

The correct Answer is:
To find the enthalpy of formation of diamond from graphite, we can use Hess's law, which states that the total enthalpy change for a reaction is the sum of the enthalpy changes for the individual steps. ### Step-by-Step Solution: 1. **Write the Given Reactions:** - For diamond: \[ C(\text{diamond}) + O_2 \rightarrow CO_2, \quad \Delta H = -395 \, \text{kJ} \] - For graphite: \[ C(\text{graphite}) + O_2 \rightarrow CO_2, \quad \Delta H = -393 \, \text{kJ} \] 2. **Identify the Target Reaction:** - We want to find the enthalpy change for the reaction: \[ C(\text{diamond}) \rightarrow C(\text{graphite}) \] 3. **Manipulate the Given Reactions:** - To find the enthalpy change for the formation of diamond from graphite, we can subtract the enthalpy change of the graphite reaction from that of the diamond reaction: \[ C(\text{diamond}) + O_2 \rightarrow CO_2 \quad (\Delta H = -395 \, \text{kJ}) \quad \text{(1)} \] \[ C(\text{graphite}) + O_2 \rightarrow CO_2 \quad (\Delta H = -393 \, \text{kJ}) \quad \text{(2)} \] 4. **Subtract the Reactions:** - We will subtract reaction (2) from reaction (1): \[ C(\text{diamond}) + O_2 - (C(\text{graphite}) + O_2) \rightarrow CO_2 - CO_2 \] - This simplifies to: \[ C(\text{diamond}) - C(\text{graphite}) = \Delta H \] 5. **Calculate the Enthalpy Change:** - The enthalpy change can be calculated as: \[ \Delta H = (-395 \, \text{kJ}) - (-393 \, \text{kJ}) = -395 + 393 = -2 \, \text{kJ} \] 6. **Final Result:** - The enthalpy of formation of diamond from graphite is: \[ \Delta H = -2 \, \text{kJ} \]

To find the enthalpy of formation of diamond from graphite, we can use Hess's law, which states that the total enthalpy change for a reaction is the sum of the enthalpy changes for the individual steps. ### Step-by-Step Solution: 1. **Write the Given Reactions:** - For diamond: \[ C(\text{diamond}) + O_2 \rightarrow CO_2, \quad \Delta H = -395 \, \text{kJ} ...
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