If `Delta_(f)H^(@)(C_(2)H_(4))` and `Delta_(f)H^(@)(C_(2)H_(6))` are `x_(1)` and `x_(2)` kcal `mol^(-1)`, then heat of hydrogenation of `C_(2)H_(4)` is :
If the heats of formation of C_(2)H_(2) and C_(6)H_(6) are 230 kJ mol^(-1) and 85 kJ mol^(-1) respectively, the DeltaH value for the trimerisation of C_(2)H_(2) is
If Delta_(f)H^(@) _(C_(3)H_(8)(g))=-85kJ moll^(-1), Delta_(f)H^(@) _(C_(3)H_(8)(g))=-104kJ mol^(-1), DeltaH for C_((s))rarr C_((g)) is 718kJ mol^(-1) and heat of formation of H- atom is 218kJ mol^(-1) , then :
When enthyne is passed through a red hot tube, then formation of benzene takes place: Delta_(f)H_((C_(2)H_(2))(g))^(Theta) = 230 kJ mol^(-1) Delta_(f)H_((C_(6)H_(6))(g))^(Theta) = 85kJ mol^(-1) Calculate the standard heat of trimerisation of ethyne to benzene: 3C_(2)H_(2)(g) rarr C_(6)H_(6)(g)
Delta_(f)H(H_(2)O) =- 68 kcal mol^(-1) and DeltaH of neutralisation is -13.7 kcal mol^(-1) , then the heat of formation of overset(Theta)OH is
The following are the heats of reactions - (i) Delta H_(f)^(@) of H_(2)O_((l))=-68.3 "K cal mol"^(-1) (ii) Delta H_("comb.")^(@) of C_(2)H_(2)=-337.2 "K cal mol"^(-1) (iii) Delta H_("comb.")^(@) of C_(2)H_(4)=-363.7 "K cal mol"^(-1) Then heat change for the reaction C_(2)H_(2)+H_(2)rarr C_(2)H_(4) is -
From the following data, calculate the standard enthalpy of formation of propane Delta_(f)H^(Theta) CH_(4) = - 17 kcal mol^(-1) Delta_(f)H^(Theta)C_(2)H_(6) =- 24 kcal mol^(-1), BE (C-H) = 99 kcal mol^(-1) (C- C) = 84 kcal mol^(-1) .
NARENDRA AWASTHI-THERMODYNAMICS-Level 3 - Match The Column