Determine enthalpy of formation for `H_(2)O_(2)(l)`, using the listed enthalpies of reaction : `N_(2)H_(4)(l)+2H_(2)O_(2)(l)toN_(2)(g)+4H_(2)O(l)`, `" "Delta_(r)H_(1)^(@)=-818kJ//mol` `N_(2)H_(4)(l)+O_(2)(g)toN_(2)(g)+2H_(2)O(l)` `" "Delta_(r)H_(2)^(@)=-622kJ//mol` `H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(l)" "Delta_(r)H_(3)^(@)=-285kJ//mol`
A
`-383` kJ/mol
B
`-187` kJ/mol
C
`-498` kJ/mol
D
None of these
Text Solution
Verified by Experts
The correct Answer is:
B
For `H_(2)(g)+O_(2)(g)rarrH_(2)O_(2)(l)` `Delta_(f)H^(@)(H_(2)O_(2),l)=Delta_(r )H_(3)^(@)+(Delta_(r )H_(2)^(@))/(2)-(Delta_(r )H_(1)^(@))/(2)`
Topper's Solved these Questions
THERMODYNAMICS
NARENDRA AWASTHI|Exercise Level 1 (Q.1 To Q.30)|6 Videos
THERMODYNAMICS
NARENDRA AWASTHI|Exercise Level 1 (Q.31 To Q.60)|2 Videos
Determine enthalpy of formation for H_(2)O_(2)(l) , using the listed enthalpies of reactions: N_(2)H_(4)(l) + 2H_(2)O_(2)(l) rarr N_(2)(g) + 4H_(2)O(l), Delta_(r)H_(1)^(@) =-818 KJ//"mol" N_(2)H_(4)(l)+O_(2)(g) rarr N_(2)(g) + 2H_(2)O(l), Delta_(r)H_(2)^(@)=-622 KJ//"mol" H_(2)(g)+(1)/(2)O_(2)(g) rarr H_(2)O(l), Delta_(r)H_(3)^(@)=-285 KJ//"mol"
Calculate the standard enthalpy of formation of CH_(3)OH(l) from the following data: CH_(3)OH(l)+3/2O_(2)(g) rarr CO_(2)(g)+2H_(2)O(l), …(i), Delta_(r)H_(1)^(Θ)=-726 kJ mol^(-1) C(g)+O_(2)(g) rarr CO_(2)(g), …(ii), Delta_(c )H_(2)^(Θ)=-393 kJ mol^(-1) H_(2)(g)+1/2O_(2)(g) rarr H_(2)O(l), ...(iii), Delta_(f)H_(3)^(Θ)=-286 kJ mol^(-1)
Calculate the enthalpy of formation of ethyl alcohol from the following data : C_(2)H_(5)OH(l) + 3O_(2)(g) to 2CO_(2)(g) + 3H_(2)O(l), Delta_(r)H^(@) = -1368.0 kJ C(s) +O_(2)(g) to CO_(2)(g), Delta_(r)H^(@) = -393.5 kJ H_(2)(g) + 1/2O_(2)(g) to H_(2)O(l), Delta_(r)H^(@) = -286.0 kJ
The heat of formation of H_(2)O_((l)) is -286.2 kJ. The heat of formation of H_(2)O_((g)) is likely to be
The enthalpy of vaporisation of liquid water using the data H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(l) , DeltaH=-285.77 kJ//mol H_(2)(g)+(1)/(2)O_(2)(g)toH_(2)O(g) , DeltaH=-241.84 kJ//mol
NARENDRA AWASTHI-THERMODYNAMICS-Level 3 - Match The Column