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Compound C_(5)H_(10) (A)underset((2) Me_(2)S//H_(2)O)overset((1)O_(3))rarrB+C Compound B and C both gives iodoform test and B also give silver mirror with ammonical silver nitrate. The structure of compound A is :
C_(6)H_(5)CHO overset(NH_(2)OH)(rarr)" A " overset(H_(2)O)(rarr) B What is not true for the compound B –
Identify the compounds (A) and (B). (A)underset("Iodoform test")underset("Gives(+ve)")((C_(11)H_(12)O)) overset(O_(3)//Red)rarr (B) underset("iodoform test")underset("Gives(+ve)")((C_(10)H_(10)O_(2))) +CH_(2)=O (B) is symmetrical p-subsituted compound. (Ignore ozonolysis of benzene ring at the initial stage).
Ph-overset(O)overset(||)(C)-CH_(3) overset(NaNO_(2))underset(HCl)(to) (A) underset("heat")overset(AC_(2)O)(to) (B)overset(H_(3)O^(+))(to)(C) Product (C) of the above reaction is :
CH_(3)CO_(2)C_(2)H_(5)overset((i) C_(2)H_(5)bar(O)overset(+)(N)a//Delta)underset((ii) H_(3)O^(+))to The structure of the compound A is
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