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Ethanol when reacts with PCl(5) gives A,...

Ethanol when reacts with `PCl_(5)` gives A, `POCl_(3)` and `HCl`. A reacts with dry `Ag_(2)O` to form B (major product) and `AgCl`. A and B respectively are :

A

`C_(2)H_(5)Cl` and `C_(2)H_(5)OC_(2)H_(5)`

B

`C_(2)H_(4)` and `C_(2)H_(5)OC_(2)H_(5)`

C

`C_(2)H_(6)` and `C_(2)H_(5)OC_(2)H_(5)`

D

`C_(2)H_(6)` and `C_(2)H_(5)NO_(2)`

Text Solution

Verified by Experts

The correct Answer is:
A

`{:(CH_(3)-CH_(2)-OH overset(PCl_(5))(rarr)CH(3)-CH_(2)Cl+POCl_(3)+HCl),(" "darrAgNO_(2)),(" "CH_(3)CH_(2)-NO_(2)):}`
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