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K(1) & K(2) for oxalic acid are 6.5 xx 1...

`K_(1)` & `K_(2)` for oxalic acid are `6.5 xx 10^(-2)` and `6.1 xx 10^(-5)` respectively . What will be the `[OH^(-)]` in a `0.01 M` solution of sodium oxalate

A

`9.6 xx 10^(-6)`

B

`1.4 xx 10^(-1)`

C

`1.2 xx 10^(-6)`

D

`1.3 xx 10^(-8)`

Text Solution

Verified by Experts

The correct Answer is:
C

The hydrolysis of `C_(2)O_(4^(2-))` is as follows
`C_(2)O_(4^(2-)) + H_(2)O hArr HC_(2)O_(4)^(-) + OH^(-)`
`[OH^(-)] = sqrt((K_(w) xx C)/(K_(2))) = sqrt((10^(-14) xx 10^(-2))/(6.1 xx 10^(-5)))`
`= 1.2 xx 10^(-6)`
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