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A body centered cubic solid is made up o...

A body centered cubic solid is made up of two elements A and B. Atoms of 'A' occupy two corners of the cube. Remaining positions of the unit cell are occupied by the atoms of 'B'. The formula of the compound in

A

`A_(6)B_(7)`

B

`A_(7)B_(4)`

C

`AB_(7)`

D

`A_(7)B`

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The correct Answer is:
To find the formula of the compound formed by elements A and B in a body-centered cubic (BCC) solid, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of BCC**: In a body-centered cubic unit cell, there are 8 corners and 1 atom at the center of the cube. 2. **Determine the Contribution of Atom A**: According to the question, atoms of element A occupy 2 corners of the cube. Each corner atom contributes \( \frac{1}{8} \) of an atom to the unit cell. - Contribution from 2 corners: \[ \text{Contribution of A} = 2 \times \frac{1}{8} = \frac{2}{8} = \frac{1}{4} \] 3. **Determine the Contribution of Atom B**: The remaining positions in the unit cell are occupied by atoms of element B. In a BCC structure, there is 1 atom at the body center. - Contribution from the body center: \[ \text{Contribution of B} = 1 \] - Total contribution of B in the unit cell: Since there are 8 corners and 1 body center, the total contribution of B can be calculated as: \[ \text{Total contribution of B} = 1 + 0 \text{ (from corners, as they are occupied by A)} = 1 \] 4. **Calculate the Total Contribution of B**: Since the corners are occupied by A, we only consider the body center for B. Therefore, the total contribution of B remains: \[ \text{Contribution of B} = 1 \] 5. **Express the Contributions in Simplified Form**: Now we have: - Contribution of A = \( \frac{1}{4} \) - Contribution of B = \( 1 \) To express these contributions in a simple whole number ratio, we can multiply both by 4 (the least common multiple): \[ A: 1 \quad \text{and} \quad B: 4 \] 6. **Write the Formula**: The formula of the compound can be expressed as: \[ \text{Formula} = A_1B_4 \text{ or simply } AB_4 \] ### Final Answer: The formula of the compound is \( AB_4 \). ---
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