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(CH(3))(2)C=CHCOCH(3) can be oxidised to...

`(CH_(3))_(2)C=CHCOCH_(3)` can be oxidised to `(CH_(3))_(2) C=CHCOOH` by

A

Chromic acid

B

`NaOl`

C

`Cu " at" 300^(@)` C

D

`KMnO_(4)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of how to oxidize `(CH₃)₂C=CHCOCH₃` to `(CH₃)₂C=CHCOOH`, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Functional Groups**: The compound `(CH₃)₂C=CHCOCH₃` contains a double bond (alkene) and a carbonyl group (ketone) in the form of `COCH₃`. 2. **Recognize the Reaction Type**: The conversion from a ketone to a carboxylic acid indicates an oxidation reaction. Specifically, we are looking to oxidize the ketone group (`COCH₃`) to a carboxylic acid group (`COOH`). 3. **Choose the Oxidizing Agent**: The iodoform reaction is a specific type of haloform reaction that can be used to oxidize methyl ketones to carboxylic acids. The reagents typically used for this reaction are iodine (I₂) and sodium hydroxide (NaOH), or sodium hypoiodite (NaOI). 4. **Perform the Reaction**: By treating the compound `(CH₃)₂C=CHCOCH₃` with sodium hypoiodite (NaOI), the methyl ketone group will be oxidized to a carboxylic acid. The overall reaction can be summarized as: \[ (CH₃)₂C=CHCOCH₃ + NaOI \rightarrow (CH₃)₂C=CHCOOH + Iodoform \] 5. **Conclusion**: The product of this reaction is `(CH₃)₂C=CHCOOH`, which is the desired carboxylic acid. ### Final Answer: The compound `(CH₃)₂C=CHCOCH₃` can be oxidized to `(CH₃)₂C=CHCOOH` by using sodium hypoiodite (NaOI) in an iodoform reaction. ---
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