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Ph-CHO+Ph-CHOoverset(Na(2)[Fe(CO)(4)])ra...

`Ph-CHO+Ph-CHOoverset(Na_(2)[Fe(CO)_(4)])rarrPh-overset(O)overset("||")C-OCH_(2)-Ph` . This reaction is known as :

A

Claisen rearrangement

B

Tischenko reaction

C

Perkin reaction

D

Cannizzaro reaction

Text Solution

Verified by Experts

The correct Answer is:
B
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Compound having -overset(O)overset(||)C-CH_(3) group reacts rapidly with halogen in presence of a base to form haloform . The reaction is known as haloform. R-overset(O)overset(||)C-CH_(3)overset(X_(2)+overset(Ө)OH)rarrR-overset(O)overset(||)C-overset(Ө)O+CHX_(3) Mechanism : Consider the following reactions : Reaction I rarr Ph-overset(O)overset(||)C-CH_(3)overset(Cl_(2),overset(Ө)OH)rarr Ph-overset(O)overset(||)C-overset(Ө)O+CHCl_(3) Reaction II rarr Ph-overset(O)overset(||)C-CD_(3)overset(Cl_(2)overset(Ө)OH)rarr,Ph-overset(O)overset(||)C-overset(Ө)O+CDCl_(3) Which of the following is correct comparison of the rate of reaction I and II ?

Ph-CH=CH-overset(O)overset(||)(C)-OH The IUPAC name is:

Ph-overset(O)overset(||)C-O-CPh_(3) overset(18)overset(H_(3)O^(oplus))rarr Product of this reaction is :

Ph-overset(O)overset(||)C-NH_2overset(POCl_3)rarr(A), Product (A) is