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An organic compound A on treatment with...

An organic compound A on treatment with `CHCl_(3)` and KOH gives B and C, both of which, in turn, gives the same compound D when distilled with Zn dust. Oxidation of D yields E of the fromula `C_(7)H_(6)O_(2)`. The Na salt of E on heating with soda lime give F which can be also be obtained by distilling A with Zn dust Identify F.

A

B

C

D

Text Solution

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The correct Answer is:
D
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An organic compound (A) on treatment with CHCl_(3) and KOH gives two compounds B and C. Both B and C give the same product (D) when distilled with zinc dust. Oxidation of D gives E having molecular formula C_(7)H_(6)O . The sodium salt of E on heating with soda-lime gives F which may also be obtained by distilling A with zinc dust. Identify A to F.

Which salt on treatment with soda lime gives ethane?

Knowledge Check

  • An organic compound (A) on treatment with CHCl_(3) and KOH gives (Y) and (Z) both of which in turn gives the same compound (T) when distilled with Zn. Oxidation of (T) Yields (S) of formula C_(7)H_(6)O_(2) . The sodium salt of (S) with sodalime gives (P) which can also be obtained by distilling (X). The compound (T) is

    A
    B
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    D
  • An organic compound (A) on treatment with CHCl_(3) and KOH gives (Y) and (Z) both of which in turn gives the same compound (T) when distilled with Zn. Oxidation of (T) Yields (S) of formula C_(7)H_(6)O_(2) . The sodium salt of (S) with sodalime gives (P) which can also be obtained by distilling (X). Compounds (Y) and (Z) could be:

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    B
    C
    D
  • An organic compound (A) on treatment with CHCl_(3) and KOH gives (Y) and (Z) both of which in turn gives the same compound (T) when distilled with Zn. Oxidation of (T) Yields (S) of formula C_(7)H_(6)O_(2) . The sodium salt of (S) with sodalime gives (P) which can also be obtained by distilling (X). The molecular weight of compound (X) is:

    A
    122
    B
    94
    C
    106
    D
    78
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