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Addition of Br(2) to cis-2-butene would ...

Addition of `Br_(2)` to cis-2-butene would give a product which is:

A

achiral

B

racemic

C

meso

D

Optically active

Text Solution

AI Generated Solution

The correct Answer is:
To determine the product of the addition of Br₂ to cis-2-butene, we can follow these steps: ### Step 1: Understand the Structure of cis-2-butene Cis-2-butene has the following structure: - It consists of four carbon atoms (C) and has a double bond between the second and third carbon atoms. - The two methyl (CH₃) groups are on the same side of the double bond, which is characteristic of the cis isomer. ### Step 2: Draw the Structure The structure can be represented as: ``` CH3 | CH3-C=C-H | H ``` ### Step 3: Addition of Br₂ When Br₂ is added to alkenes, the reaction proceeds via an anti-addition mechanism. This means that the bromine atoms will add to opposite sides of the double bond. ### Step 4: Mechanism of Anti-Addition 1. The double bond attacks one of the bromine atoms, leading to the formation of a cyclic bromonium ion. 2. The other bromine atom will then attack from the opposite side, leading to the formation of a vicinal dibromide. ### Step 5: Determine the Product For cis-2-butene, the anti-addition will lead to the formation of two different stereoisomers: - One product will have bromine atoms added to the opposite sides of the double bond. The resulting products will be: - One product will have the configuration (2R,3S) and the other will have (2S,3R), which are enantiomers. ### Step 6: Identify the Nature of the Product Since the product consists of two enantiomers, it is classified as a racemic mixture (a 1:1 mixture of two enantiomers), which is not optically active. ### Conclusion The addition of Br₂ to cis-2-butene results in a racemic mixture of brominated products. ### Final Answer The product is a **racemic mixture**. ---

To determine the product of the addition of Br₂ to cis-2-butene, we can follow these steps: ### Step 1: Understand the Structure of cis-2-butene Cis-2-butene has the following structure: - It consists of four carbon atoms (C) and has a double bond between the second and third carbon atoms. - The two methyl (CH₃) groups are on the same side of the double bond, which is characteristic of the cis isomer. ### Step 2: Draw the Structure ...
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