Taking into account the stability of various cycloalkanes and carbocations, as well as the rules governing mechanisms of carbocation rearrangements, what is the most likely product of this reaction?
A
B
C
D
Text Solution
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The correct Answer is:
b
Ring expansion take place .
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Under common reaction conditions, a carboncation rearranges to another carbocation of equal or greater stability. For example secondary carbocation will rearrange to a tertiary carbocation. It will not rearrange to a less stable primary carbocation. This generalization is not absolute, and because there is not is a high energy barrier to the rearrangement of carbocations, rearrangement to a less stable cation can occur if it offers the chance to forme a more stable product. In which of the following cations rearrangement takes place most rapidly?