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cis-2-buteneoverset(HBr)underset("Peroxi...

cis-2-butene`overset(HBr)underset("Peroxide")(to)`product, Product of the reaction is:

A

Racemic

B

Diastereomers

C

Meso

D

Pure enantiomers

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To determine the product of the reaction of cis-2-butene with HBr in the presence of peroxide, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is cis-2-butene, which has the structure: \[ \text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 \] - In the cis configuration, the two methyl (CH₃) groups are on the same side of the double bond. 2. **Understand the Reaction Conditions**: - The reaction occurs in the presence of peroxide, which indicates that a free radical mechanism will be involved. 3. **Free Radical Mechanism**: - In the presence of peroxide, HBr will dissociate into H• (hydrogen radical) and Br• (bromine radical). - The double bond in cis-2-butene will undergo homolysis, forming two radicals: a carbon radical and a hydrogen radical. 4. **Formation of Radicals**: - The double bond can break in such a way that either carbon can become a radical. This leads to the formation of two possible radicals: - CH₃-CH•-CH₂-CH₃ (with a radical on the second carbon) - CH₃-CH₂-CH•-CH₃ (with a radical on the third carbon) 5. **Radical Combination**: - The H• radical can add to one of the carbon radicals formed, while the Br• radical can add to the other carbon. - Due to the symmetry of cis-2-butene, both combinations will yield the same product: - CH₃-CH(Br)-CH₂-CH₃ 6. **Chirality and Optical Activity**: - The product has one chiral center at the carbon that is bonded to the bromine atom. This means that the product will be optically active. - The presence of a chiral center allows for the formation of two enantiomers (mirror images). 7. **Final Product**: - The final product of the reaction is 2-bromobutane, which exists as a racemic mixture of two enantiomers due to the presence of the chiral center. ### Conclusion: The product of the reaction of cis-2-butene with HBr in the presence of peroxide is a racemic mixture of 2-bromobutane, which is optically active due to the presence of a chiral carbon.

To determine the product of the reaction of cis-2-butene with HBr in the presence of peroxide, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactant is cis-2-butene, which has the structure: \[ \text{CH}_3-\text{CH}=\text{CH}-\text{CH}_3 ...
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