CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-CH_(3) overset((NH_(4))_(2)CO_(3))underset(Delta) to (A) overset(C Cl_(3) CO_(2)Na) underset(Delta) to underset(("major"))((B)) Product (B) of above reaction is :
Oxymercuration demercuratioon reaction is process of additon H_(2)O according to Markownikoff's rule without any rearrangemnbt CH_(3)(-CH=CH_(2)(Hg(Oac)_(2),H_(2)O)rarr(NaBH_(4),OH)CH_(3)-overset(OH)overset(|)CH-CH_(3) Machanism: Base OH is used to neutralise H^(opluse) proudeced during the reaction CH_(3)-overset(CH_(3))overset(|)underset(Ch_(3))underset(|)C-CH=CH_(2)overset(Hg(OAC)_(2),CH_(3)OH)underset(NaBH_(4),OH)rarrProduct:
CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(CH)-overset(KMnO_(4))to (A) overset(H^(+))underset(Delta)to (B) overset(HBr) underset(RO OR) to (C) Product (C) in the above reaction is:
Identify the product in the following reaction CH_(3)-underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-CH=CH_(2)overset("Hg (OAc)"_(2l)H_(2)O)rarroverset(NaBH_(4))rarr 3, 3-Dimethyl - 1 - butene