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Which of the following would not rearran...

Which of the following would not rearrange to a more stable form?

A

B

C

D

Text Solution

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The correct Answer is:
To determine which of the given carbocations would not rearrange to a more stable form, we need to analyze the stability of each carbocation and whether they can undergo rearrangement. ### Step-by-Step Solution: 1. **Identify the Carbocations**: We need to look at the structures of the carbocations provided in the question. Each carbocation has a different degree of substitution (1°, 2°, 3°). 2. **Evaluate Stability**: - **Carbocation A**: If it is a 2° carbocation, it can rearrange to a more stable 3° carbocation by a hydride shift. Thus, it can rearrange. - **Carbocation B**: This is a 1° carbocation. If a hydride shifts to it, it can become a 2° carbocation, which is more stable. Therefore, it can rearrange. - **Carbocation C**: This carbocation is part of a ring structure. If it undergoes a ring expansion, it does not rearrange in the traditional sense (like hydride shifts). Instead, it expands into a larger ring. Therefore, it does not rearrange to a more stable carbocation. - **Carbocation D**: This is a 2° carbocation. If a hydride shifts, it can rearrange to a more stable 3° carbocation. 3. **Conclusion**: Based on the analysis, the carbocation that would not rearrange to a more stable form is **Carbocation C**. ### Final Answer: **Carbocation C** would not rearrange to a more stable form. ---

To determine which of the given carbocations would not rearrange to a more stable form, we need to analyze the stability of each carbocation and whether they can undergo rearrangement. ### Step-by-Step Solution: 1. **Identify the Carbocations**: We need to look at the structures of the carbocations provided in the question. Each carbocation has a different degree of substitution (1°, 2°, 3°). 2. **Evaluate Stability**: ...
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