Home
Class 12
CHEMISTRY
2KMnO(4) +3H(2)SO(4) rarr K(2)SO(4)+2MnS...

`2KMnO_(4) +3H_(2)SO_(4) rarr K_(2)SO_(4)+2MnSO_(4)+3H_(2)O+5[O]`
`X+O rarr Y`
X can't be:

A

CO

B

`SO_(4)^(2-)`

C

`SO_(3)^(2-)`

D

`C_(2)O_(4)^(2-)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to identify which compound X cannot be when it is oxidized by the oxidizing agent KMnO4 in the presence of H2SO4. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction provided is: \[ 2KMnO_4 + 3H_2SO_4 \rightarrow K_2SO_4 + 2MnSO_4 + 3H_2O + 5[O] \] Here, KMnO4 acts as an oxidizing agent. 2. **Identifying Oxidation**: Oxidation involves an increase in the oxidation state of a substance. In this case, we need to determine the oxidation states of the elements in the potential compounds that could be X. 3. **Analyzing Possible Candidates for X**: We need to check various candidates for X to see which one cannot be oxidized. - **Candidate 1: \( SO_4^{2-} \)** (Sulfate Ion) - The oxidation state of sulfur (S) in \( SO_4^{2-} \): \[ \text{Let oxidation state of S be } x. \] \[ x + 4(-2) = -2 \implies x - 8 = -2 \implies x = +6 \] - Since sulfur is in its highest oxidation state (+6), it cannot be oxidized further. Therefore, \( SO_4^{2-} \) cannot be X. - **Candidate 2: \( SO_3^{2-} \)** (Sulfite Ion) - The oxidation state of sulfur (S) in \( SO_3^{2-} \): \[ \text{Let oxidation state of S be } x. \] \[ x + 3(-2) = -2 \implies x - 6 = -2 \implies x = +4 \] - The oxidation state of sulfur is +4, which can be oxidized to +5 or +6. Therefore, \( SO_3^{2-} \) can be X. 4. **Conclusion**: Based on the analysis, the only candidate that cannot be oxidized by KMnO4 is \( SO_4^{2-} \). Thus, the answer is: \[ \text{X cannot be: } SO_4^{2-} \]

To solve the given question, we need to identify which compound X cannot be when it is oxidized by the oxidizing agent KMnO4 in the presence of H2SO4. ### Step-by-Step Solution: 1. **Understanding the Reaction**: The reaction provided is: \[ 2KMnO_4 + 3H_2SO_4 \rightarrow K_2SO_4 + 2MnSO_4 + 3H_2O + 5[O] ...
Promotional Banner

Topper's Solved these Questions

  • P BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Reasoning Type|11 Videos
  • P BLOCK ELEMENTS

    GRB PUBLICATION|Exercise Multiple Objective Type|47 Videos
  • METALLUGY

    GRB PUBLICATION|Exercise Subjective type|1 Videos
  • SOLID STATE

    GRB PUBLICATION|Exercise All Questions|267 Videos

Similar Questions

Explore conceptually related problems

Mn(OH)_(2)+H_(2)SO_(4) to MnSO_(4)+2H_(2)O

Balance the following reactions by oxidation number method KMnO_(4) + H_(2)SO_(4) +HCl rarr K_(2) SO_(4) + MnSO_(4) + H_(2) O + Cl_(2)

10 ml of "0.02 M KMnO"_(4) is required to oxidize 20 ml of oxalic acid 25 ml of the same oxalic acid sol was used to neutralize 20 ml of NaOH of unknown strength. Calculate the amount of NaOH present per litre of solution. 2KMnO_(4)+3H_(2)SO_(4)rarrK_(2)SO_(4)+2MnSO_(4)+3H_(2)O+5[O] {:(COOH),(|),(COOH):}+[O]rarr 2CO_(2)+H_(2)O {:(COOH),(|),(COOH):}+2NaOHrarr +{:(COOH),(|),(COOH):}+2H_(2)O

Na_(2)SO_(3)+H_(2)O_(2) rarr Na_(2)SO_(4) +H_(2)O , in reaction

H_(2)O_(2)+2KIoverset(40% "yield")rarrI_(2)+2KOH H_(2)O_(2)+2KMnO_(4)+3H_(2)SO_(4)overset(50% "yield")rarr K_(2)SO_(4)+2MnSO_(4)+3O_(2)+4H_(2)O 150mL of H_(2)O_(2) sample was divided into two parts. First part was treated with KI and formed KOH required 200 mL of M//2H_(2)SO_(4) for neutralisation. Other part was treated with KMnO_(4) yielding 6.74 litre of O_(2) at 1 atm. and 273 K. Using % yield indicated find volume strength of H_(2)O_(2) sample used.

Balance the following equations : (i) KMnO_(4) + H_(2)SO_(4) + H_(2)O_(2) to K_(2)SO_(4) + MnSO_(4) + H_(2)O + O_(2) (ii) KMnO_(4) + KCl + H_(2)SO_(4) to MnSO_(4) + K_(2)SO_(4) + H_(2)O + Cl_(2) (iii) MnO_(2) + H_(2)O_(2) to MnO_(4)^(-) + MnO_(4)^(-) + H_(2)O (Basic medium)

GRB PUBLICATION-P BLOCK ELEMENTS-Subjectice Type
  1. 2KMnO(4) +3H(2)SO(4) rarr K(2)SO(4)+2MnSO(4)+3H(2)O+5[O] X+O rarr Y ...

    Text Solution

    |

  2. Find the number of reagents which would lead to unsymmetrical cleavage...

    Text Solution

    |

  3. Find the number of species which undergo hydrolysis at room temperatur...

    Text Solution

    |

  4. Consider the ions : S(2)O(3)^(2-)(X) and S(2)O(4)^(2-)(Y). How many st...

    Text Solution

    |

  5. Beryllium chloride exists as polymeric chain having fromula (BeCl(2))(...

    Text Solution

    |

  6. For the given reactions: (a) C(x)H(y) +(x+(y)/(4))O(2) rarr xCO(2)+(...

    Text Solution

    |

  7. Find the total number of species which would undergo disproportionatio...

    Text Solution

    |

  8. Find the sum of triangular BO(3) unit and BO(4) tetrahedral unit in bo...

    Text Solution

    |

  9. Total number of CN^(-) ion that are present in ICN(liq.)

    Text Solution

    |

  10. How many of the following reaction would produce phosphine gas ? (a)...

    Text Solution

    |

  11. How many of the following compounds will decolourize the colour of aci...

    Text Solution

    |

  12. B(2)H(6)+NH(3) rarr X "( ionic compound) " overset("heated") rarr Y+H(...

    Text Solution

    |

  13. Find the number of sigma bond and lone pair respectively in hydrated b...

    Text Solution

    |

  14. Find the total number of compounds which produce N(2) gas on heating. ...

    Text Solution

    |

  15. How many of the following have zero dipole moment? C Cl(4),,C(2)O(3...

    Text Solution

    |

  16. (a) Number of ions which are regarded as ionic carbides amongst (C^(...

    Text Solution

    |

  17. Please help Santa and Banta to decode the lock of their car XYZTU {...

    Text Solution

    |

  18. Find the number of compounds among the following whose hydrolysis is a...

    Text Solution

    |

  19. In how many of the following non-metal showns -3 oxidation state ? C...

    Text Solution

    |

  20. Find the total number of elements which show allotropy. C,N,P ,As,Sb...

    Text Solution

    |

  21. How many stoal effective number of O-atoms, Si-atoms and changes that ...

    Text Solution

    |