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When 100 mL of an aqueous of H(2)O(2) is...

When `100 mL` of an aqueous of `H_(2)O_(2)` is titrated with an excess of `KI` solution in dilute `H_(2)O_(2)`, the liberated `I_(2)` required `50 mL` of `0.1 M Na_(2) S_(2)O_(3)` solution for complete reaction. Calculate the percentage strength and volume strength of `H_(2)O_(2)` solution.

A

`10%`

B

`20%`

C

`5%`

D

`40%`

Text Solution

Verified by Experts

The correct Answer is:
A

No. of milli equivalents `Cu^(+2) = 100`
`Cu^(+2) = 100 xx 63.5 xx 10^(-3) = 6.35g`
`159.5g` of `CuSO_(4)` should contain `= 63.5g` of copper but only `6.35gCu` is present
% purity `=(6.35)/(63.5) xx 100 = 10%`
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When 100 " mL of " an aqueous solution of H_2O_2 is titrated with an excess of KI solution in dilute H_2SO_4 , the liberated I_2 required 50 " mL of " 0.1 M Na_2S_2O_3 solution for complete reaction. Calculate the percentage strength and volume strength of H_2O_2 solution.

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