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0.1M solution of KI reacts with excess o...

0.1M solution of KI reacts with excess of `H_(2)SO_(4)` and `KIO_(3)` solutions, according to equation
`5I^(-)+IO_(3)^(-)+6H^(+)to3I^(2)+3H_(2)O`, which of the following statements is /are correct:

A

200mL of the KI solution react with `0.004` mole `KIO_(3)`

B

100mL of the KI solution reacts with `0.006` mole of `H_(2)SO_(4)`

C

`0.5` litre of the KI solution produced `0.005` mole of `I_(2)`

D

Equivalent weight of `KIO_(3)` is equal to `(("Molecular weight")/(5))`

Text Solution

Verified by Experts

The correct Answer is:
A, B, D

`5I^(-) + IO_(3)^(-) + 6H^(+) rarr 3I_(2) +3H_(2)O`
`("Moles of Ki used")/("Moles of" KIO_(3) used) = 5`
Valency factor for `KIO_(3) = 5`
`:. Ew = (M)/(5)`
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