Home
Class 11
CHEMISTRY
The vanderwaal's constant a=2.095 "lit"^...

The vanderwaal's constant `a=2.095 "lit"^(-2) atm "mol"^(-1) and b=0.0189 "lit mol"^(-1)` respectively. Calculate the inversion temperature.

Text Solution

Verified by Experts

Given:
`a=2.095 "lit"^(2) "atm mol"^(-)`
`R=0.821 dm^(3) "atm lit" K^(-1) "mol"^(-1)`
`b=0.0189 "lit mol"^(-1)`
Sol `T_(i) =(2a)/(Rb)`
`=(2xx2.095)/(0.821xx0.0189)=2700.28 K`
`T_(1) =2700.28 K`
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    SURA PUBLICATION|Exercise ADDITIONAL LONG ANSWERS|12 Videos
  • ENVIRONMENTAL CHEMISTRY

    SURA PUBLICATION|Exercise 5 MARKS|1 Videos
  • GOVT. MODEL QUESTION PAPER - I

    SURA PUBLICATION|Exercise PART-D|16 Videos

Similar Questions

Explore conceptually related problems

Vanderwaal's constant for a gas a=3.67 atm "lit"^() "mol"^(-1) b=0.0408 '"lit mol"^(-1) . Find the critical temperautre and critical pressure of the gas.

DeltaH and DeltaS for the reaction Ag_(2)O_((s))rarr2Ag_((s))+1/2O_(2_((g))) " are "30.56 kJ mol^(-1) and 66.0 Jk^(-1) mol^(-1) respectively. Calculate the temperature at which the free energy for this reaction will be zero. What will be the direction of reaction at this temperature and at temperature below this and why ? Given: DeltaH=30.56kJ mol^(-1)=30560 J mol^(-1) DeltaS=66.0JK^(-1)mol^(-1) DeltaG=0

The standard enthalpies of formation of SO_2 and SO_3 are -297 "kJ mol"^(-1) 396 "kJ mol"^(-1) respectively. Calculate the standard enthalpy of reaction for the reaction: SO_2 + 1//2O_2 to SO_3

Vanderwaal's constant for a gas (g) are a=6.34 atm "lit"^(-2), and b =52.6 ml "mol"^(-1) . Find the critical temperature and critical pressure of the gas.

Vanderwaal's constants for hydrogen chloride gas are a = 3.67 atm lit^(-2) and b = 40.8 ml mol^(-1) . Find the critical temperature and critical pressure of the gas.

Vanderwaal's constant in litre atmosphere per mole for carbon dioxide are a = 3.6 and b = 4.28 xx 10^(-2) . Calculate the critical temperature and critical volume of the gas. R = 0.0820 lit atm K^(-1). Mol^(-1)

SURA PUBLICATION-GASEOUS STATE-NUMERICAL PROBLEMS
  1. A neon-dioxygen mixture contains 60.8 dioxygen and 167.5 g neon. If pr...

    Text Solution

    |

  2. If a gas diffuses at the rate of one-half as fast as O(2), find the mo...

    Text Solution

    |

  3. 75 ml of gas A effuses through a pin hole in 73 seconds the same volum...

    Text Solution

    |

  4. Vanderwaal's constant for a gas (g) area=6.34 atm "lit"^(-2), and b =5...

    Text Solution

    |

  5. Vanderwaal's constant for a gas a=3.67 atm "lit"^() "mol"^(-1) b=0.040...

    Text Solution

    |

  6. The vanderwaal's constant a=2.095 "lit"^(-2) atm "mol"^(-1) and b=0.01...

    Text Solution

    |

  7. If a scuba diver takes a breath at the surfae filling his lungs with 5...

    Text Solution

    |

  8. Inside a certain automobile engingen, the valume of air in a cylinder ...

    Text Solution

    |

  9. Effect of temperature on volume of the gas to verify Charles law All...

    Text Solution

    |

  10. Find the ratio of effusion rates of hydrogen and krypton gas.

    Text Solution

    |

  11. If the wather balloon at a pressure 0.0965 atm. At ground level has a ...

    Text Solution

    |

  12. At sea level a balloon has volume of 785xx10^(-3) dm^(3). What will be...

    Text Solution

    |

  13. When the temperature of a gas increases from 0^(@)C the valume of the ...

    Text Solution

    |

  14. In an experiment of verification of Charle's law, the following are th...

    Text Solution

    |

  15. A helium filled balloon had a volume of 400 ml, when it is cooled to -...

    Text Solution

    |

  16. Suppose a 375 ml sample of neon gas at 78^(@)C is cooled to 22^(@)C at...

    Text Solution

    |

  17. Which of following flasks has higher pressure , 5.00 L containing 4.1...

    Text Solution

    |

  18. Which of following flasks has higher pressure , 10.0 L containing 56....

    Text Solution

    |

  19. At what temperature would 4.285g o foxygen gas O(2) exert a pressure o...

    Text Solution

    |

  20. For a gaseous mixtue of 2.41g of helium and 2.79g of neon in an evacua...

    Text Solution

    |