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Calculate lattice energy for the change,...

Calculate lattice energy for the change,
`Li^(+)(g)+Cl^(-) (g) rarr LiCl(g)`
Given that
`{:(DeltaH_("sublimation")" of "Li=160.67 kJ mol^(-1)",",,DeltaH_("Dissociation")" of "Cl_(2) =244.34 kJ mol^(-1)","),(DeltaH_("ionisation")" of "Li(g)=520.07 kJ mol^(-1)",",,DeltaH_(E.A)" of "Cl(g)= -365.26 kJ mol^(-1)","),(DeltaH_(f)" of "LiCl(s)= -401.66 kJ mol^(-1)",",,):}`

Text Solution

Verified by Experts


`DeltaH_(f)=DeltaH_(1)+DeltaH_(2)+DeltaH_(3)+2DeltaH_(4)+u`
`-795=121+2422+242.8+(2xx355)+u`
`-795=2785.8-710+u`
`-795=2075.8+u`
`u=-795-2075.8=-2870.8 kJ .mol^(-1)`
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Calculate the lattice enthalpy of CaCl_(2) given that the enthalpy of : i) Sublimation of Ca in "121.8 kJ mol"^(-1) ii) Dissociation of Cl_(2) to 2Cl is "242.8 kJ mol"^(-1) iii) Ionisation of Ca" to "Ca^(2+)" is 2422 kJ mol"^(-1) iv) Electron gain for Cl" to "Cl^(-)" is - 355 kJ mol"^(-1) v) DeltaH_(f)^((o))" overall is "-"795 kJ mol"^(-1)

Calculate the lattice energy of formation of NaCl from the following data : Na_((s)) +1//2Cl_(2(g)) to NaCl_((s)) Delta H_(f) -411.3 KJ.mol^(-1) Heat of sublimation of Na_((s)) = 108 . 7 kJ mol ^(-1) Ionisation energy of Na_((g)) = 49.5.0 kJ mol^(-1) Dissociation energy of Cl_(2(g)) = 244 kJ mol^(-1) Electron affinity of Cl_((g)) = - 349 . 0 kJ mol^(-1)

Calculate the lattice energy of CaCl_2 from the given data. Ca_((s)) + Cl_(2(g)) to CaCl_(2(s)) DeltaH_f^0 =-795 "kJ mol"^(-1) Sublimation : Ca_((s)) to Ca_((g)) " " DeltaH_1^0=+121 "kJ mol"^(-1) Ionisation : Ca_((g)) to Ca_((g))^(2+) +2e^(-) " " DeltaH_2^0=+2422 "kJ mol"^(-1) Dissociation : Cl_(2(g)) to 2Cl_((g)) " " DeltaH_3^0=+242.8 "kJ mol"^(-1) Electron affinity : Cl_((g)) + e^(-) to Cl_((g))^(-) " " DeltaH_4^0=-355 "kJ mol"^(-1)

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Calculate the change of entropy for the process , water (liq) to water (vapor,373) involving DeltaH_("vap")=40850 J mol ^(-1) " at " 373K.

What is the equilibrium constant K_(eq) for the following reaction at 400 K. 2NOCl_((g)) hArr 2NO_((g)) +Cl_(2(g)) , given that DeltaH^0=77.2 "kJ mol"^(-1) and DeltaS^0=122 "JK"^(-1) "mol"^(-1) .

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