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The standard heat of formation of H(2)O(...

The standard heat of formation of `H_(2)O_((l))` from its elements `H_(2) and O_(2)` is `-290.83 kJmol^(-1)` and the standard entropy change for the same reaction is `-330 JK^(-1)" at " 25^(@)C.` Will the reaction be spontaneous at `25^(@)C`.
Given: `DeltaH^(@)=-290.83 kJmol^(-1)`
`=-290830Jmol^(-1)`
`DeltaS^(@)=-330JK^(-1)`
`T=25^(@)C=298K`

Text Solution

Verified by Experts

`DeltaG^(@)=DeltaH^(@)-TDeltaS^(@)`
`=-290830-298(-330)`
`=-290830+98340=-192490`
`DeltaG^(@)=-192490 J mol^(-1)`
Since `DeltaG^(@)` is negative , the reaction is spontaneous.
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