Home
Class 11
CHEMISTRY
One mole of PCl(5) is heated in one litr...

One mole of `PCl_(5)` is heated in one litre closed container. If 0.6 mole of chlorine is found at equilibrium, calculate the value of equilibrium constant.

Text Solution

Verified by Experts

Given that `[PCl_(5)]_("initial")=("1 mole")/("1 dm"^(3))`
`" "[Cl_(2)]_(eq)=0.6" mol dm"^(-3)`
`PCl_(5)hArrPCl_(3)+Cl_(2)`
`[PCl_(3)]_(eq)=0.6" mole dm"^(-3)`
`[PCl_(5)]_(eq)=0.4" mole dm"^(-3)`
`:.K_(C)=([PCl_(3)][Cl_(2)])/([PCl_(5)])=(0.6xx0.6)/(0.4)`
`K_(c)=0.9`.
Promotional Banner

Topper's Solved these Questions

  • PHYSICAL AND CHEMICAL EQUILIBRIUM

    SURA PUBLICATION|Exercise ADDITIONAL QUESTIONS (Choose the correct answer)|53 Videos
  • PHYSICAL AND CHEMICAL EQUILIBRIUM

    SURA PUBLICATION|Exercise Very short answer question|18 Videos
  • PHYSICAL AND CHEMICAL EQUILIBRIUM

    SURA PUBLICATION|Exercise Creative questions (HOTS)|11 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS

    SURA PUBLICATION|Exercise NUMERICAL PROBLEMS|2 Videos
  • PUBLIC EXAMINATION - MARCH 2019

    SURA PUBLICATION|Exercise Part - IV|19 Videos

Similar Questions

Explore conceptually related problems

One mole of CO_(2) contains

For the reaction A+BhArr3C at 25^(@)C , a 3 litre volume reaction vessel contains 1,2 and 4 moles of A,B and C respectively at equilibrium, calculate the equilibrium constant K_(c) of the reaction at 25^(@)C .

SURA PUBLICATION-PHYSICAL AND CHEMICAL EQUILIBRIUM-Evaluation (Write brief answer to the following questions)
  1. Consider the following reactions, CaCO(3)(s)hArrCaO(s)+CO(2)(g) In...

    Text Solution

    |

  2. Consider the following reactions, S(s)+3F(2)(g)hArrSF(6)(g) In ea...

    Text Solution

    |

  3. State law of mass action.

    Text Solution

    |

  4. Explain how will you predict the direction of a equilibrium reaction.

    Text Solution

    |

  5. Derive a general expression for the equilibrium constant K(P) and K(C)...

    Text Solution

    |

  6. Write a balanced chemical equation for a equilibrium reaction for whic...

    Text Solution

    |

  7. What is the effect of added inert gas on the reaction at equilibrium a...

    Text Solution

    |

  8. Derive the relation between K(P) and K(C').

    Text Solution

    |

  9. One mole of PCl(5) is heated in one litre closed container. If 0.6 mol...

    Text Solution

    |

  10. For the reaction SrCO(3)(s)hArrSrO(s)+CO(2)(g), the value of equil...

    Text Solution

    |

  11. To study the decomposition of hydrogen iodide, a student fills an evac...

    Text Solution

    |

  12. Oxidation of nitrogen monoxide was studied at 200^(@)C with initial pr...

    Text Solution

    |

  13. 1 mol of CH(4), 1 mole of CS(2) and 2 mol of H(2)S are 2 mol of H(2) a...

    Text Solution

    |

  14. At particular temperature K(C)=4xx10^(-2) for the reaction H(2)S(g)h...

    Text Solution

    |

  15. 28 g of nitrogen and 6 g of hydrogen were mixed in a 1 litre closed co...

    Text Solution

    |

  16. The equilibrium for the dissociation of XY(2) is given as, 2XY(2)(g)...

    Text Solution

    |

  17. A sealed container was filled with 1 mol of A(2)(g) 1 mol B(2)(g) at 8...

    Text Solution

    |

  18. Deduce the Vant Hoff equation.

    Text Solution

    |

  19. The equilibrium constant K(P) for the reaction N(2)(g)+3H(2)(g)hArr2NH...

    Text Solution

    |

  20. The partial pressure of carbon dioxide in the reaction CaCO(3)(s)hAr...

    Text Solution

    |