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An organic compound (A) with molecular f...

An organic compound (A) with molecular formula `C_(2)H_(5)Cl` reacts with KOH gives compounds (B) and with alcoholic KOH gives compound (C). Identify (A), (B) and (C).

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Compound (A) of molecular formula C_(7)H_(8) when treated with air in presence of V_(2)O_(5) at 773 K gives a compound (B) of molecular formula C_(7)H_(6)O , which has the smell of bitter almonds. Alkaline KMnO_(4) oxidises compound (B) to ( C) of molecular formula C_(7)H_(6)O_(2) . Compound (B) on treatment with N_(2)H_(4) and KOH gives back compound (A). Identify (A), (B) & ( C) and explain the reactions.

An organic compound of molecula formula C_(6)H_(5)O"Na" is heated with CO_(2) at 400 K gives compound (A) of molecular formula C_(7)H_(5)O_(3)Na . Compound (A) on treating with HCl gives (B). B on further reactions wiith NaOH / CaO gives compound (C ) of molecular formula C_(6)H_(6)O which on treatment with nitrous acid at 200 K gives compound (D ). Identify (A), (B) , ( C) and (D) are explain the reactions.

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