Zn+ "Conc." HNO(3) rarr...

`Zn+ "Conc." HNO_(3) rarr`

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`Zn+Conc. HNO_(3) rarr Zn(NO_(3))_(2) +NH_(4)(NO_(3))_(2)+H_(2)uarr`

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Zn + "dil " HNO_(3) rarr

Assertion (A): Phenol on nitration with Conc. HNO_(3) and H_(2)SO_(4) give a mixture of o and p-nitro phenol. Reason (R): -OH group is deactivating group.

0.185 g of an organic compound when treated with Conc. HNO_(3) and silver nitrate gave 0.320g of silver bromide. Calculate the % of bromine in the compound. (Ag=108, Br=80).

(b) A aromatic hydrocarbon (A) of molecular formula C_(6)H_(6) reacts with Conc. HNO_(3) and Conc. H_(2)SO_(4) gives (B) of formula C_(6)H_(5)O_(2)N . (B) on reaction with Sn//HCl gives (C ) of formula C_(6)H_(7)N which answers carbylamine reaction. (C ) on treatment with chloroform and alkali gives (D ) of formula C_(7)H_(5)N . Identify A, B, C, D and explain the reactions involved.

Complete the following reactions . Mg+HNO_(3) rarr

SURA PUBLICATION-P-BLOCK ELEMENTS - II-EVALUATION (EVALUATE YOURSELF)

Zn + "dil " HNO(3) rarr
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Zn+ "Conc." HNO(3) rarr
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