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An organic compound (A) C(2)H(3)OCl on t...

An organic compound (A) `C_(2)H_(3)OCl` on treatment with Pd and `BaSO_(4)` gives (B) `C_(2)H_(4)O` which answers iodoform test. (B) when treated with conc. `H_(2)SO_(4)` undergoes polymerisation to give ( C) a cyclic compound. Identify (A), (B) and ( C) and explain the reactions.

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(i) Compound (A) must be acetyl chloride which undergoes Rosenmund's reduction giving acetaldehyde.
`underset((A))(CH_(3)COCl)overset(Pd//BaSO_(4))tounderset((B))(CH_(3)CHO)`
(B) undergoes iodoform reaction
`underset((B))(CH_(3)CHO)overset(I_(2)//NaOH)tounderset("Iodoform")(CHI_(3))+HCOONa`
(ii) Acetaldelyde (B) undergoes ploymerisation giving a cyclic compound

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Compound (A) of molecular formula C_(7)H_(8) when treated with air in presence of V_(2)O_(5) at 773 K gives a compound (B) of molecular formula C_(7)H_(6)O , which has the smell of bitter almonds. Alkaline KMnO_(4) oxidises compound (B) to ( C) of molecular formula C_(7)H_(6)O_(2) . Compound (B) on treatment with N_(2)H_(4) and KOH gives back compound (A). Identify (A), (B) & ( C) and explain the reactions.

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SURA PUBLICATION-CARBONYL COMPOUND-PROBLEMS FOR PRACTICE
  1. An organic compound (A) of molecular formula C(7)H(6)O is not reduced ...

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  2. An organic compound A (C(7)H(6)O) reduces Tollen's reagent. On treatin...

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  3. An organic compound A (C(7)H(6)O) forms a bisulphite. A when treated w...

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  4. An aromatic aldehyde (A) of molecular formula C(7)H(6)O which has the ...

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  5. An organic compound (A) C(7)H(8), on oxidation at 773K in the presence...

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  6. Compound A with molecular formula C(7)H(6)O reduces Tollen's reagent a...

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  7. Compound A having the molecular formula C(2)H(4)O reduces Tollen's rea...

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  8. An aromatic compound (A) with molecular formula C(7)H(6)O has the smel...

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  9. An organic compound (A) C(2)H(3)OCl on treatment with Pd and BaSO(4) g...

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  10. Compound (A) of molecular formula C(7)H(8) when treated with air in pr...

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  11. An organic compound (A) with molecular formula C(3)H(6)O undergoes iod...

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  12. Compound A of molecular formula C(3)H(6)O does not reduce Tollen's rea...

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  13. An organic compound A (C(2)H(3)N) on reduction with SnCl(2)//HCl gives...

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  14. Compound (A) with molecular formula C(2)H(4)O reduces Tollen's reagent...

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  15. An organic compound (A) of molecular formula C(7)H(6)O is called as oi...

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  16. An organic compound (A) of molecular formula C(7)H(8) on oxidation wit...

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  17. An organic compound (A) C(7)H(6)O reduces Tollen's reagent. Compound (...

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  18. An organic compound A of molecular formula C(3)H(6)O answer iodoform t...

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  19. Compound (A) with Molecular formula C(7)H(6)O does not reduce Fehling'...

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