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An organic compound C7H9N anwers carbyla...

An organic compound `C_7H_9N` anwers carbylamine reaction but produces primary alcohol with nitrous acid. The compound may be

A

p-toludine

B

o-toluidine

C

benzylamine

D

m-toludine

Text Solution

Verified by Experts

The correct Answer is:
C
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The organic compound that undergoes carbylamine reaction is

(b) A aromatic hydrocarbon (A) of molecular formula C_(6)H_(6) reacts with Conc. HNO_(3) and Conc. H_(2)SO_(4) gives (B) of formula C_(6)H_(5)O_(2)N . (B) on reaction with Sn//HCl gives (C ) of formula C_(6)H_(7)N which answers carbylamine reaction. (C ) on treatment with chloroform and alkali gives (D ) of formula C_(7)H_(5)N . Identify A, B, C, D and explain the reactions involved.