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An aromatic primary amine A with molecul...

An aromatic primary amine A with molecular formula `C_6H_7N` undergoes diazotisation to give B.B when treated with hypophosphorous acid gives C. Identify A, B and C.

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(i) An aromatic primary amine (A) is identified as aniline `C_6H_5NH_2`.
(ii) Aniline undergoes diazotisation to give benzene diazonium chloride `C_6H_5N_2Cl` and it is (B).
`{:(C_6H_5NH_2underset(0^(@) C)overset(NaNO_2+HCl)(to)C_6H_5N_2Cl),(" Aniline Benzene diazonium chloride(B) "):}`
(iii) Benzene diazonium chloride on treatment with hypophosphorous acid gives benzene `C_6H_6` and it is (C ).
`{:(C_6H_5N_2Clunderset(2[H])overset(H_3PO_2)(to)C_6H_6+N_2uparrow+HCl),(" Benzene(C ) "):}`.
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SURA PUBLICATION-ORGANIC NITROGEN COMPOUNDS-VERY SHORT ANSWERS
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  2. C6H5CH2NH2overset(HNO2)(to)A overset((O))(to)B underset(HCl)overset(Zn...

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  3. An aromatic primary amine A with molecular formula C6H7N undergoes dia...

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  4. An aromatic simplest nitro compound A on reduction using Sn and HCl gi...

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  5. An organic compound A of molecular formula C2H5ON treated with bromine...

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  6. CH3NO2overset(Sn2"/"HCl)(to)A underset(" alcoholic KOH ") overset(CHCl...

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  7. C6HG5NH2 underset(273K, HCl) overset(HNO2)(to)A underset(Cu2(CN)2)over...

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  8. An aromatic hydrocarbon A on nitration gives B which is known as oil o...

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  9. Identify (A),(B) and (C ) CH4 underset(400^(@)C)overset(HNO3)(to)A o...

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  10. C6H5CONH2 underset(KOH)overset(Br2)(to)X underset(HCl)overset(HNO2)(to...

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  11. C2H3N underset(" Ether ")overset(LiAl"/"H4)(to)B overset(HNO2)(to) I...

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  12. Identify the compounds A,B,C in the following reactions: CH3CONH2 un...

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  13. Identify the compounds A,B,C in the following reactions: C2H5Cl over...

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  14. Bring aout the conversion of Chlorobenzene to aniline.

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  15. Find 'X' and 'Y' CH3Br overset(NaN3)(to) 'X' overset(LiAlH4)(to)'Y'?

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  16. Identify A and B in the following sequence of reactions. CH4underset...

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  17. Convert methyl amine (1^(@) " primary amine ) to "2^(@),3^(@) amine an...

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  19. Aniline reacts with bromine water to give a white precipitate. Write...

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  20. Write a note on Libermann's nitroso test.

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