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Compound (A)C(6)H(12)O is optically acti...

Compound (A)`C_(6)H_(12)O` is optically active . Compound (A) give negative Tollens test and positive test with 2-4-di-nitro phenyl hydrazine . Identify A.

A

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-underset(CH_(3))underset(|)(CH)-CH_(3)`

B

`CH_(3)-overset(O)overset(||)(C)-underset(CH_(2)-CH_(3))underset(|)(CH)-CH_(3)`

C

`H-overset(O)overset(||)(C)-CH_(2)-underset(CH_(2) - CH_(3))underset(|)(CH)-CH_(3)`

D

`CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-CH_(2)-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
B
(b) Optically active compound are b & c but only b give negative tollen test .
Ketones give negative Tollen's test and positive 2,4-DNP test .
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