Home
Class 11
CHEMISTRY
Prove that pH+pOH=pK(w) at 298 K....

Prove that `pH+pOH=pK_(w)` at 298 K.

Text Solution

Verified by Experts

The ionic product of water is given by `[H^(+)][OH^(-)]=K_(w)=1.0xx10^(-14)` at 298 K
Taking log on both sides, `log_(10)[H^(+)]+log_(10)[OH^(-)]=log_(10)K_(w)=log_(10)1.0xx10^(-14)`
Multipling by -ve sign, `-log_(10)[H^(+)]-log_(10)[OH^(-)]=log_(10)K_(w)=-14.0000`
wkt by definition, `pH+pOH=pK_(w)=14`.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL EQUILIBRIUM

    SUBHASH PUBLICATION|Exercise THREE MARK QUESTIONS AND ANSWERS :|14 Videos
  • CHEMICAL EQUILIBRIUM

    SUBHASH PUBLICATION|Exercise NUMERICAL PROBLEMS|34 Videos
  • CHEMICAL EQUILIBRIUM

    SUBHASH PUBLICATION|Exercise NUMERICAL PROBLEMS|34 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    SUBHASH PUBLICATION|Exercise THREE MARKS QUESTIONS|28 Videos
  • CHEMICAL THERMODYNAMICS

    SUBHASH PUBLICATION|Exercise Numerical problems :|38 Videos

Similar Questions

Explore conceptually related problems

The solubility product of a sparingly soluble metal hydroxide, M(OH)_(2) at 298 K is 5xx10^(-16)mol^(3)dm^(-9) . The ph value of its aqueous and saturated solution is :

The following reaction is performed at 298 K 2NO(g)+O_(2)(g)hArr 2NO_(2)(g) . The standard free energy of formation of NO (g) is 86.6 kJ / mol at 298 K. What is the standard free energy of formation of NO_(2)(g) at 298 K ? (K_(p)=1.6xx10^(12)) .

Which of the following solution will have pH = 9 at 298 K ?

The pH of D_(2)O and H_(2)O at 298 k is

Calculate the pH of a buffer mixture of 0.05 M NH_(4)Cl and 0.12 M NH_(4)OH at 298 K. (Dissociation constant of ammonium hydroxide at 298 K is 1.8xx10^(-5) ).

The lowest degree of permagnetism per mole of the compound at 298 K will be shown by

EMF of the cell |Ag|AgNO_(3)(0.1M)||K Br(1 N),AgBr(s)|Ag is -0.6V at 298K AgNO_(3) is 80% and KBr is 60% dissociated. Calculate a. Solubility and b. K_(sp) of AgBr at 298 K .