Home
Class 11
CHEMISTRY
State with equations what happens when b...

State with equations what happens when borax is heated on a plantium wire loop and then to the resulting transparent mass a minute amount of CuO is added and the mixture is again heated first in an oxidising flame and then in the reducing flame of a Bunsen Burner .

Text Solution

Verified by Experts

When borax is heated on a platinum wire loop a transparent glassy bead is formed
`Na_(2)B_(4)O_(7).10H_(2)O underset(-10H_(2)O) overset("heat")rarrNa_(2)B_(4)O_(7)overset("heat")rarr underset("Transparent glassy bead")ubrace("Sod.metaborate Boric anhydride")2NaBO_(2)+B_(2)O_(3)`
When this transparent glassy bead is heated with CuO in the oxidising flame it imparts blue colour to the bead due to the formation of cupric metaborate
`CuO+B_(2)O_(3)underset("flame") overset("Oxidising") (rarr)underset("Cupric metaborate (blue)")(Cu(BO_(2))_(2))`
However when cupric metaborate is heated in the reducing flame of the Bunsen burner the blue cupric metaborate is reduced by carbon present in the flame first to colourless cuprous metaborate and then to copper metal which produces a red colour.
`underset(("Blue"))underset("Cupric metaborate")(2Cu(BO_(2))_(2))+Crarr underset(("Colourless"))underset("Cuprous metaborate")(2CuBO_(2))+B_(2)O_(3)+CO`
`2CuNO_(2)Crarrunderset("Red")underset("Copper metal") (Cu)+B_(2)O_(3)+CO`
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK ELEMENTS

    SUBHASH PUBLICATION|Exercise Two mark questions and answers|33 Videos
  • HYDROGEN

    SUBHASH PUBLICATION|Exercise Three marks questions and answers|15 Videos
  • PUE DEPT. MODEL QUESTION PAPER

    SUBHASH PUBLICATION|Exercise PART-C|14 Videos
SUBHASH PUBLICATION-P-BLOCK ELEMENTS-Three mark questions and answers
  1. Discuss the basic unit and structure of silicates.

    Text Solution

    |

  2. How does metallic character vary among group 14 elements ? How is it r...

    Text Solution

    |

  3. Write a note on the structure of Fullerene. Mention any two of its app...

    Text Solution

    |

  4. Explain the structure of graphite giving the reason for its softness a...

    Text Solution

    |

  5. Explain the structure of diamond giving the reason for its harness as ...

    Text Solution

    |

  6. Give is the difference in the structure of the following pair of comou...

    Text Solution

    |

  7. Explain the formation of (i) water gas (ii) producer gas. Give their u...

    Text Solution

    |

  8. What happens when CO(2) is passed through lime water (i) for a short ...

    Text Solution

    |

  9. What is dry ice ? Why is it called so ? How to prepare a pure sample o...

    Text Solution

    |

  10. What happens when ? (i) Quick lime is heated with coke ? (ii) Carbon m...

    Text Solution

    |

  11. Give a comparative account of the chemistry of carbon and silicon with...

    Text Solution

    |

  12. A certain salt X gives the following results (i) Its aqueous solution ...

    Text Solution

    |

  13. (a ) Carbon dioxide is non -polar while water is polar. What conclusio...

    Text Solution

    |

  14. A white crystalline solid A dissolves in water to give an alkaline sol...

    Text Solution

    |

  15. Mention three important uses of borax.

    Text Solution

    |

  16. What is allotropy ? Give examples of allotropes.

    Text Solution

    |

  17. Give three uses each of the different allotropic forms of carbon.

    Text Solution

    |

  18. How is boron obtained from borax ? Give chemical equations with reacti...

    Text Solution

    |

  19. What is inorganic benzene ? Why is it so called ? How will you get it ...

    Text Solution

    |

  20. State with equations what happens when borax is heated on a plantium w...

    Text Solution

    |