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Show that chromates and dichromates are ...

Show that chromates and dichromates are interconvertible.

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The chromate and dichromates are interconvertible in aqueous solution depending upon pH of the solution.
At low pH (acidic medium) :
Chromate converts into dichromate
`2CrO_(4)^(2-)+2H^(+)rarrCr_(2)O_(7)^(2-)+H_(2)O`
At high pH (alkaline medium) :
dichromate is converted into chromate
`Cr_(2)O_(7)^(2-)+2OH^(-)rarr2CrO_(4)^(2-)+H_(2)O`
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SUBHASH PUBLICATION-THE 'd' - AND 'f' - BLOCK ELEMENTS -Question and Answer
  1. What are interstitial compounds?

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  2. How is potassium dichromate prepared from chromite are ?

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  3. Show that chromates and dichromates are interconvertible.

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  4. Give the structure of chromate ion?

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  5. Give two example to show that potassium dichromate is an oxidising age...

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  6. How is potassium permanganate manufactured from MnO(2) (pyrolusite)?

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  7. Name a compound which is isostructural with KMnO(4).

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  8. What happens when potassium permanganate crystals are heated?

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  9. What is the shape of manganate and permanganate ions? Write structures...

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  10. What is the magnetic nature of manganate and permanganate ions.

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  11. Give four examples to show that acidified KMnO(4) is an oxidising agen...

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  12. What is lanthanoid contraction? Mention the cause for it.

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  13. What is lanthanoid contraction? Write the general oxidation state of a...

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  14. Give two consequences of lanthanoid contraction.

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  15. What happens when lanthanoids are heated in Oxygen

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  16. What happens when lanthanoids are heated in Nitrogen

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  17. What happens when lanthanoids are heated in Halogen

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  18. What happens when lanthanoids are heated in Carbon?

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  19. How lanthanoids reacts with water and dil. Acids?

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  20. What is mischmetall? Give its one use.

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