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Give reason. Atomic size of 4d and 5d ...

Give reason.
Atomic size of 4d and 5d series elements are almost the same.

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Due to lanthanoid contraction.
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Give reason : (i) Most of the transition metals have high melting point and boiling point (ii) 2^(nd) ionization enthalpy of Cu is exceptionally high. (iii) atomic size of 4d- and 5d-series elements are almost the same.

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Observe the given table and question: answer the following {:("Elements", A, B, C, D, E),("Atomic number", 11,4,2,7,19):} Identify the two elements that belong to the same period and the two elements that belong to the same group. Give reason for your conclusion.

How would you account for the following: (i) The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as those of the corresponding members of the second (4d) series. (ii) The E^0 value for the Mn^(3+)//Mn^(2+) couple is much more positive than that for Cr^(3+)//Cr^(2+) couple or Fe^(3+)//Fe^(2+) couple.

Given below are some elements of the Modern Periodic Table: ""_(4)Be, ""_(26)Fe.""_(14)Si, ""_(19)K ""_(20)Ca i) Select the element that has one electron in the outermost shell and write its electronic configuration. ii) Select two elements that belong to the same group. Give reason. iii) Select two elements that belong to the same period. Which one of the two has a bigger atomic size?

How would you account for the following: (i) Among lanthanoids, Ln (III) compounds are predominant. However, occasionally in solutions or in solid compounds, +2 and +4 ions are also obtained. (ii) The E_(M^(2+)//M)^(0) for copper is positive (0.34 V). Copper is the only metal in the first series of transition elements showing this behaviour. (iii) The metallic radii of the third (5d) series of transition metals are nearly the same as those of the corresponding members of the second series.

SUBHASH PUBLICATION-THE 'd' - AND 'f' - BLOCK ELEMENTS -Question and Answer
  1. What happens when lanthanoids are heated in Carbon?

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  2. How lanthanoids reacts with water and dil. Acids?

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  3. What is mischmetall? Give its one use.

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  4. What is actinoid contraction? Why actinoid contraction is greater than...

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  5. Give reason: Actinoid contraction is greater from element to element t...

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  6. Give general oxidation state of actinoids. Why actinoids shows variabl...

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  7. Zr and Hf have almost identical atomic radii. Give reason.

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  8. Give reasons: Actinoids show variable oxidation states.

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  9. Give reasons: Zr and Hf have almost identical radii.

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  10. Give reason: Why Lanthanoids are less reactive than actinoids.

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  11. Out of the following elements identify the element which does not exhi...

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  12. Give Reason. Most of the transition metals have high melting point a...

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  13. Give Reason. Second ionisation enthalpy of copper is exceptionally h...

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  14. Give reason. Atomic size of 4d and 5d series elements are almost the...

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  15. Study of actinoid elements is difficult. Give two reasons.

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  16. Give reasons : Cerium (Ce) exhibits +4 oxidation state

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  17. Among Fe^(2+) and Fe^(3+) which is more stable? Give reason.

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  18. Give reason: Mn exhibits the higher oxidatoin state of +7 among 3d s...

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  19. Give reason: Cu^(2+) is paramagnetic and Cu^(+) is diamagnetic.

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  20. Give reason 'transition metals generally form coloured compound'.

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